闅ㄨ憲姘磋硣婧愮殑绶婄己鍜屾按鐠�(hu谩n)澧冩薄鏌撶殑鍔犲妵銆傝繎骞翠締(l谩i)宸ユキ(y猫)姘磋檿鐞�鎶€琛�(sh霉)鏈変簡寰堝ぇ鐨勭櫦(f膩)灞曪紟鐩墠鐨勬妧琛�(sh霉)涓昏鏈夊寲瀛�(xu茅)娉�銆佺墿鐞嗘硶銆佺墿鐞嗗寲瀛�(xu茅)娉曠瓑鍜屽悇绋柟娉曠殑闆嗘垚绲勫悎锛庡ぇ閮藉皯涓嶄簡鐢ㄥ埌鍖栧(xu茅)鏂规硶鍗虫姇鍔犺棩鍔�锛屽洜?y脿n)妯楊彆涓旂幆N铏曠悊宸ヨ棟绨�(ji菐n)鍠�锛屽崰鍦伴潰绌嶅皯锛岃檿鐞嗛€熷害蹇�銆傝檿鐞嗘垚鏈浉灏�(du矛)杓冧綆鐨勬垚鐔熸柟娉曘€傝€屾敼鎬ф穩绮夋按铏曠悊鍔戜綔鐐哄ぉ鐒堕珮鍒嗗瓙纰虫按鍖栧悎鐗╂敼鎬ц€屽緱鐨勬按铏曠悊鍔�锛屽畠灏�(du矛)鐠�(hu谩n)澧冪劇(w煤)姣掔劇(w煤)瀹�锛屼笖鍏惰檿鐞嗘畼?ji膩n)顝濆鏅冣懜顚濋敐鍒�?銆傚洜姝�锛屼笉?hu矛)灏�(du矛)鐠�(hu谩n)澧冮€犳垚浜屾姹℃煋锛庢湁钁楀唬闂婄殑鎳�(y墨ng)鐢ㄥ墠鏅�銆�

1銆佽畩鎬ф穩绮変綔鐐虹诞鍑濆姂鐨勬噳(y墨ng)鐢�

澶╃劧楂樺垎瀛愮诞鍑濆姂鑷�7O骞翠唬浠ヤ締(l谩i)宸叉妸鐮旂┒閲嶅績杞�(zhu菐n)绉诲埌鏀规€т笂銆傛穩绮夋敼鎬х诞鍑濆姂閬告搰鎬уぇ銆佺劇(w煤)姣�銆佸児(ji脿)寤夌墿璞愩€佺劇(w煤)姣�銆佸彲闄嶈В锛岄€氶亷閱氬寲銆侀叝鍖�銆佹帴鏋濆叡鑱氱瓑鍖栧(xu茅)鏀规€э紟鍙互寰楀埌澶氱ó鎬ц兘鍎�(y艒u)鐣扮殑璁婃€ф穩绮�銆傚洜鍏锋湁鑹ソ鐨勭稉(j墨ng)婵�(j矛)鍍�(ji脿)鍊煎拰绀炬渻(hu矛)鍍�(ji脿)鍊艰€屽挨鐐哄紩浜烘敞鐩�銆傛穩绮夊熀澶╃劧楂樺垎瀛愭敼鎬х诞鍑濆姂锛庝害灞按婧舵€ц仛鍚堢墿锛屾湁鑹ソ鐨勬按鍒嗘暎鎬�锛屽叿鏈夊绋犱綔鐢�銆傚畠涓嶅儏閫氶亷鑷韩鐨勭矘搴﹀鍔犳按鐩哥殑绮樺害锛庡苟鍙互鍜屾按涓殑鍒嗘暎鐩革紝姘翠腑鍏跺畠楂樺垎瀛愬寲鍚堢墿鐧�(f膩)鐢熶綔鐢�銆傚皫(d菐o)鑷村绋犳晥鏋溿€傜敱浜庡畠灞挵(hu谩n)澧冩柊鏉愭枡銆傚湪娑傛枡銆佺矘鍚堝姂銆侀噰娌�銆侀鍝佸伐妤�(y猫)涓兘鏈夊緢澶х殑鐝�(xi脿n)瀵�(sh铆)鎳�(y墨ng)鐢ㄥ児(ji脿)鍊笺€傛穩绮夊熀鎺ユ灊鍏辫仛澶╃劧楂樺垎瀛愭敼鎬х诞鍑濆姂鍙垎鐐洪潪闆㈠瓙鍨�銆侀櫧(y谩ng)闆㈠瓙鍨嬨€佸叐鎬х诞鍑濆姂銆�

1.1銆侀潪闆㈠瓙娣€绮夋敼鎬х诞鍑濆姂

闈為洟瀛愭穩绮夋敼鎬х诞鍑濆姂鍙互鍘婚櫎姘翠腑鐨勭劇(w煤)姗�(j墨)璩�(zh矛)椤�?锛涢o(w煤)姗�(j墨)涓€鏈夋(j墨)璩�(zh矛)娣峰悎楂旂郴锛宲H鍊奸仼鐢ㄨ寖鍦嶈純瀵�銆備笉鍙楅噾灞洟瀛愮殑褰遍熆銆傛槸閫氶亷鑱氬悎鐗╅珮鍒嗗瓙鐨勯暦(zh菐ng)閺堟妸姹℃按涓殑瑷卞绱�(x矛)灏忛?锛涜洿妞Р顝冭兌缃刾鍦ㄤ竴璧疯€屽舰鎴愭灦姗嬶紝鏄竴绋诞鍑濊兘鍔涢潪甯稿挤(qi谩ng)鐨勭诞鍑濆姂銆�

1.2銆侀櫚闆㈠瓙娣€绮夋敼鎬х诞鍑濊崐

鑰冩叜姹℃按鎳告诞鐗╁強鑶犻珨姹℃煋鐗╃殑鐗规€э紟闄�(y谩ng)闆㈠瓙姹℃煋鐗╃殑娓呴櫎鍜屽ぉ鐒堕珮鍒嗗瓙鏈韩鐗规湁鐨勫劒(y艒u)鑹€ц唱(zh矛)锛庝互鍙婄従(xi脿n)鍦ㄦ柊鍨嬬诞鍑濆姂澶у鏁�(sh霉)鏄潪闆㈠瓙鍨嬬诞鍑濆姂锛庤繎骞惧勾锛庝互娣€绮夌偤鍩烘潗鐨勯櫚闆㈠瓙澶╃劧楂樺垎瀛愮诞鍑濆姂寰楀埌浜嗗湅(gu贸)鍏�(n猫i)澶栫殑寤ｆ硾闂�(gu膩n)娉�銆傞櫚闆㈠瓙娣€绮夌诞鍑濆姂绋杓冨锛屼富瑕佹湁娣€绮夌７閰搁叝銆佹穩绮夐粌鍘熼吀閰拰缇х敳鍩烘穩绮�銆傚彲浠ヤ綔鐐洪瓪椤炲姞宸ュ粻寤㈡按銆佸睜瀹板牬(ch菐ng)寤㈡按銆佺櫦(f膩)閰靛伐寤犲虎姘淬€佺礄婕垮虎姘�銆侀噾灞�?g貌u)U姘�銆佹偿婕跨殑绲嚌鍔�銆傞倓鍙互浣滅偤娴父閬哥う鐨勬矇闄嶅姂锛庡洖鏀堕媮绀︾煶涓殑閶�銆傛矇闄嶇叅绀︽礂鐓ゅ虎姘翠腑鐨勭叅绮�銆傜爺鍒剁殑纾烽叝娣€绮夌诞鍑濆姂锛庡皪(du矛)寤㈢礄鑴ⅷ鍜岀簿绱�(x矛)鍖栧伐寤犵殑宸ユキ(y猫)寤㈡按閫�(j矛n)琛岃檿鐞�锛屾敹鍒版槑椤殑鏁堟灉锛屽苟鎺㈣◣浜嗙７閰搁叝娣€绮夎檿鐞嗛粦娑插拰绮剧窗(x矛)鍖栧伐寤犲虎姘寸殑鏈€浣虫浠�銆�

1.3銆侀櫧(y谩ng)闆㈠瓙娣€绮夌诞鍑濆姂

闄�(y谩ng)闆㈠瓙娣€绮夋槸鑳洪鍖栧悎鐗╄垏娣€绮夊垎瀛愮殑缇ュ熀鍦ㄥ牽鍌寲浣滅敤涓嬪弽鎳�(y墨ng)鐢熸垚鐨勯啔鍖栨穩绮夎鐢熺墿闄�(y谩ng)闆㈠瓙娣€绮夋寜鍏堕櫧(y谩ng)闆㈠瓙鎬у挤(qi谩ng)搴︾殑涓嶅悓鍙互鍒嗙偤瀛ｉ姩楣介櫧(y谩ng)闆㈠瓙娣€绮�銆佸彅鑳洪菇闄�(y谩ng)闆㈠瓙娣€绮夈€佷徊鑳洪菇闄�(y谩ng)闆㈠瓙娣€绮�銆佷集鑳洪菇闄�(y谩ng)闆㈠瓙娣€绮夌瓑銆傚叾涓噸榛�(di菐n)鐢ㄤ簬绲嚌鍔戠殑鏄閵ㄩ菇闄�(y谩ng)闆㈠瓙娣€绮�銆傞櫧(y谩ng)闆㈠瓙娣€绮夊彲鑸囨按涓井绮掕捣闆昏嵎涓拰鍚搁檮姗嬫灦浣滅敤锛屼娇楂旂郴涓殑寰矑鑴┅(w臎n)銆佺诞鍑�锛屽緸鑰岄櫎鍘绘按涓嚫娴浐楂旓紟闄嶄綆姘寸殑婵佸害銆�

浠ユ穩绮夌偤鍩烘湰鍘熸枡锛庨€氶亷鍖栧(xu茅)鏀规€х爺鍒跺嚭瀛ｉ姩楣藉瀷鏈夋(j墨)闄�(y谩ng)闆㈠瓙鏀规€ч珮鍒嗙诞鍑濆姂锛庡皪(du矛)楂樺逗鍦熸嚫婵佹恫鏈夎壇濂界殑绲嚌闄ゆ縼鏁堟灉銆傚湪鎶曞姞閲�4mg锛廘鏅�(sh铆)銆傝檿鐞嗘按涓婃竻娑蹭綑婵佸害鍙湁3锛�2ntu銆傛瘮杓冨(sh铆)椹�(y脿n)绲�(ji茅)鏋滐紝琛ㄦ槑鑷埗瀛ｉ姩楣藉瀷鏈夋(j墨)闄�(y谩ng)闆㈠瓙鏀规€ч珮鍒嗗瓙绲嚌鐨勭诞鍑濇€ц兘鍎�(y艒u)浜庤仛涓欑儻閰拌兒PAM銆傞€欐槸鐢变簬瀛ｉ姩楣藉瀷鏈夋(j墨)闄�(y谩ng)闆㈠瓙鏀规€ч珮鍒嗗瓙绲嚌鍔戝儏鍏锋湁姗嬭伅(li谩n)浣滅敤锛庤€屼笖鍥犻浕鑽蜂腑鍜岃兘鍔涘挤(qi谩ng)锛庝娇寰楅绮掗枔鐢�(ch菐n)鐢熷唬娉涚殑灞€閮ㄦ帴瑙哥诞鍑�锛岃€屽皫(d菐o)鑷寸诞鍑濇矇闄嶉€熷害蹇�锛岀诞楂斿瘑瀵�(sh铆)銆傝€岀敤鑱氫笝鐑叞鑳篜AM鏅�(sh铆)闆栫敘(ch菐n)鐢熺殑绲湗(tu谩n)杓冪矖澶э紟鍥犻亷澶х殑绲湗(tu谩n)绲�(ji茅)妲�(g貌u)鏈�(hu矛)闄嶄綆绲湗(tu谩n)鐨勫瘑搴﹀拰寮�(qi谩ng)搴︼紟鍥犺€屽皫(d菐o)鑷磋仛涓欑儻閰拌兒PAM鐨勬矇闄嶉€熷害涓嶅鑷埗瀛ｉ姩楣藉瀷鏈夋(j墨)闄�(y谩ng)闆㈠瓙鏀规€ч珮鍒嗗瓙绲嚌鍔戠殑蹇€�

1.4鍏╂€ф穩绮夌诞鍑濆姂

姘存憾鎬у叐鎬ч珮鍒嗗瓙鏄寚鍦ㄩ珮鍒嗗瓙閺堢瘈(ji茅)涓婂悓鏅�(sh铆)鍚湁姝�銆佽矤(f霉)鍏╃ó闆昏嵎鍩哄湗(tu谩n)鐨勬按婧舵€ч珮鍒嗗瓙锛岃垏鍍呭惈鏈変竴绋浕鑽风殑姘存憾鎬ч櫚闆㈠瓙鎴栭櫧(y谩ng)闆㈠瓙鑱氬悎鐗╃浉姣旓紟鎬ц兘杓冪偤鐛�(d煤)鐗�锛屽彲鐢ㄤ綔绲嚌鍔�銆佹薄娉ヨ劔姘村姂鍜岄噾灞洟瀛愬惛闄勫姂绛�銆傜敤浣滅诞鍑濆姂鐨勫叐鎬ч珮鍒嗗瓙鍥犲叿鏈夐仼鐢ㄤ簬闄�銆侀櫧(y谩ng)闆㈠瓙鍏卞瓨鐨勬薄鏌撻珨绯�銆侀仼鐢ㄧ殑pH鍊艰寖鍦嶅鍙婃姉楣芥€уソ绛夌壒榛�(di菐n)锛屾垚鐐哄湅(gu贸)鍏�(n猫i)澶栫殑鐮旂┒鐔遍粸(di菐n)銆傚湪铏曠悊姹℃按鏅�(sh铆)涓嶅儏鍙互鍒╃敤娣€绮夌殑鍗婂墰鎬ч張鍜屾煍鎬ф敮閺堝皣姹℃按涓嚫娴殑椤嗙矑閫氶亷鏋舵⿱浣滅敤绲嚌娌夐檷涓嬩締(l谩i)锛岀诞楂旇純澶�锛屾矇闄嶉€熷害蹇�锛岀诞楂斿瘑瀵�(sh铆)锛岃€屼笖鍥犲叾甯舵湁鐨勬サ鎬у熀鍦�(tu谩n)锛庡張鍙互閫氶亷鍖栧(xu茅)鍜岀墿鐞嗕綔鐢ㄩ檷浣庢薄姘翠腑鐨凜OD銆丅OD璨�(f霉)鑽�銆傚叾闄�(y谩ng)闆㈠瓙鍓囧彲浠ユ崟鎹夋按涓殑鏈夋(j墨)鎳告诞闆滆唱(zh矛)锛庨櫚闆㈠瓙鍓囧彲浠ヤ績閫�(j矛n)鐒�(w煤)姗�(j墨)鎳告诞鐗╃殑娌夐檷銆傚彲浠ヨ檿鐞嗚ū澶氬叾浠栫诞鍑濆姂闆ｄ互铏曠悊鐨勬按璩�(zh矛)杓冨京(f霉)闆滅殑姹℃按銆傜壒鍒ュ皪(du矛)姹℃偿鑴按锛屼笉鍍呮湁闆绘€т腑鍜�銆佸惛闄勬⿱鑱�(li谩n)浣滅敤锛岃€屼笖鏈夊垎瀛愰枔鐨勭簭绻炲寘瑁逛綔鐢�锛屼娇铏曠悊鐨勬薄娉ラ绮掔矖澶э紝鑴按鎬уソ锛屽嵆浣挎槸灏�(du矛)涓嶅悓鎬ц唱(zh矛)鐨勪笉鍚岃厫鏁楃▼搴︾殑姹℃偿涔熻兘鐧�(f膩)鎻純濂界殑鑴按鍔╂烤浣滅敤銆�

2銆佽畩鎬ф穩绮変綔鐐哄惛闄勫姂鐨勬噳(y墨ng)鐢�
澶╃劧鑱氱硸椤為珮鍒嗗瓙鍏锋湁渚�(l谩i)婧愬唬娉涖€佹槗鐛插緱銆佹槗闄嶈В绛夌壒榛�(di菐n)锛庢墍浠ュ皪(du矛)鍏舵敼鎬х殑鐮旂┒鍙婃噳(y墨ng)鐢ㄩ€愭几澧炲鍏舵敼鎬ф柟娉曚富瑕佹槸鍒╃敤鍚堟垚鐨勬垨澶╃劧鐨勮仛绯栭珮鍒嗗瓙锛岄€氶亷楂樺垎瀛愬寲瀛�(xu茅)鍙嶆噳(y墨ng)锛屽紩鍏ュ叿鏈夊惛闄勫姛鑳界殑鍋�(c猫)鍩轰締(l谩i)鍚堟垚楂樺垎瀛愬惛闄勫姂銆傛穩绮夊熀閲嶉噾灞洟瀛愬惛闄勫姂鍙互鍒嗙偤鍏╂€ф穩绮夊惛闄勫姂銆侀櫚闆㈠瓙娣€绮夊惛闄勫姂銆佹帴鏋濇穩绮夊惛闄勫姂銆佷腑鎬ф穩绮夊惛闄勫姂銆侀櫧(y谩ng)闆㈠瓙鍚搁檮鍔戠瓑锛屼互涓嬪皣鍒嗗垾浠嬬垂銆�

2.1銆佸叐鎬ф穩绮夊惛闄勫姂

鎵€璎傜殑鍏╂€ф穩绮夊惛闄勫姂鏄寚鍚屾檪(sh铆)灏囬櫚銆侀櫧(y谩ng)闆㈠瓙鍩哄湗(tu谩n)寮曞叆鍒版穩绮夎憽鑱氱硸鍒嗗瓙閺堜笂銆傚父鐢ㄧ殑闄伴洟瀛愬熀鍦�(tu谩n)鏈夌７閰搁叝鍩�銆佺晶鍩虹瓑锛庡父鐢ㄧ殑闄�(y谩ng)闆㈠瓙鍩哄湗(tu谩n)鏈夊彅鑳哄熀銆佸閵ㄥ熀绛夈€傚叐鎬у熀鍦�(tu谩n)鐨勫紩鍏ュ彲浠ヤ娇闆㈠瓙浜ゆ彌銆佽灟鍚堢瓑鍚搁檮浣滅敤鏂瑰紡鍚屾檪(sh铆)鐧�(f膩)鐢燂紟鑸囧柈涓€鍩哄湗(tu谩n)鐨勬敼鎬ф穩绮夌浉姣斿ぇ澶ф彁楂樹簡鍚搁檮閲忋€傜爺绌剁祼(ji茅)鏋滆〃鏄庡惛闄勯亷绋嬭垏婵冨害鐩搁棞(gu膩n)鑰屼笖鏄惛鐔辩殑锛庡苟閬靛惊Langmuir鍚搁檮绛夋韩寮�锛屽惛闄勫閲忛毃钁楀彇浠ｅ熀鐨勫鍔犺€屾彁楂樸€傚惛闄勪簡閲嶉噾灞洟瀛愮殑鍏╂€ф穩绮�锛屽彲鍐嶇敓锛岄噸寰�(f霉)浣跨敤銆�

2.2銆侀櫚闆㈠瓙娣€绮夊惛闄勫姂

鐢变簬澶ч儴鍒嗛噾灞洟瀛愰兘鏄互闄�(y谩ng)闆㈠瓙鐨勫舰寮忓瓨鍦ㄧ殑銆傛墍浠ラ櫚闆㈠瓙娣€绮夊皪(du矛)浜庨噸閲戝爆闆㈠瓙鐨勫幓闄ゆ湁寰堝ソ鐨勬晥鏋�銆傚父鐢ㄧ殑闄伴洟瀛愬熀鍦�(tu谩n)鏈夌７閰搁叝鍩恒€佺晶鍩�銆佺：閰搁叝鍩虹瓑銆�

Kim鍜孡im鍏堢敤POC13鍒跺倷鍑轰氦鑱�(li谩n)娣€绮夛紟鐒跺悗鍐嶅埗鍌欏嚭DS鍦�0锛�02锝�0锛�08涔嬮枔鐨勪氦鑱�(li谩n)缇х敳鍩烘穩绮夛紟骞剁爺绌跺叾灏�(du矛)浜屽児(ji脿)閲戝爆闆㈠瓙鐨勫惛闄勶紟鐧�(f膩)鐝�(xi脿n)鍚搁檮閲忛毃钁楀彇浠ｅ害鐨勫澶ц€屽崌楂橈紟鍚搁檮鐨勯噾灞洟瀛愬彲浠ュ湪寮遍吀鐨勬浠朵笅鑴檮銆傚洓宸濆ぇ瀛�(xu茅)鐨勫妷鏄庤彲绛夌爺绌朵簡缇х敳鍩烘穩绮夊皪(du矛)Cr(III)銆丄I(III)鐨勫惛闄勫湏锛屼篃鐧�(f膩)鐝�(xi脿n)浜嗗悓妯ｇ殑瑕�(gu墨)寰�銆傞將娆ｇ瓑鐮旂┒浜嗘穩绮夐粌鍘熼吀閰皪(du矛)浜庨噸閲戝爆闆㈠瓙鐨勫惛闄勶紟绲�(ji茅)鏋滆〃鏄庢穩绮夐粌鍘熼吀閰殑鍒跺倷姊濅欢銆佺敤閲忓強閲嶉噾灞洟瀛愮殑婵冨害灏�(du矛)鍚搁檮鎬ц兘鏈夐噸瑕佸奖闊匡紟鍚搁檮鍔戠殑鍚搁檮瀹归噺鍙仈(d谩)鍒�4mmol锛廹宸﹀彸銆侹weon绛夊埗鍌欎簡涓嶅悓鍙栦唬搴︾殑姘у寲娣€绮夌惀鐝€閰搁叝锛庡苟鐮旂┒浜嗗畠鍊戝皪(du矛)浜屽児(ji脿)閲戝爆闆㈠瓙鐨勫惛闄勶紟鐧�(f膩)鐝�(xi脿n)鐞ョ弨閰告穩绮夐叝灏�(du矛)浜庡惛闄勯墰闆㈠瓙闈炲父鏈夋晥锛庤€屾哀鍖栨穩绮夊皪(du矛)浜庡惛闄勯妳闆㈠瓙闈炲父鏈夋晥锛庡惛闄勫潎閬靛惊Langmuir鍚搁檮绛夋韩寮�銆�

2.3銆侀櫧(y谩ng)闆㈠瓙娣€绮夊惛闄勫姂

閲嶉噾灞洟瀛愬Cr(VI1涔熷彲浠ヤ互闄伴洟瀛愮殑褰㈠紡鍑虹従(xi脿n)鍦ㄦ按婧舵恫涓紟鍥犳甯跺閵ㄥ熀闄�(y谩ng)闆㈠瓙鍩哄湗(tu谩n)鐨勯櫧(y谩ng)闆㈠瓙娣€绮変篃鍙互鍚搁檮閲嶉噾灞洟瀛�銆俋u绛変汉鐮旂┒浜嗕氦鑱�(li谩n)闄�(y谩ng)闆㈠瓙娣€绮夊皪(du矛)浜嶤rfVI1鐨勫惛闄勫槻锛岀櫦(f膩)鐝�(xi脿n)鍚搁檮鍙互鍦ㄥ緢鐭殑鏅�(sh铆)闁撳収(n猫i)閬�(d谩)鍒板钩琛�锛屽惛闄勯噺闅ㄨ憲鍙栦唬搴︾殑澧炲姞鑰屽鍔狅紟鍚搁檮璩囨枡閬靛惊Langmuir鍚搁檮绛夋韩寮�銆�

2.4銆侀潪闆㈠瓙娣€绮夊惛闄勫姂

寮曞叆姘ㄥ熀銆侀啗鍩虹瓑娲绘€у熀鐨勬敼鎬ф穩绮夊惛闄勫姂绋变箣鐐洪潪闆㈠瓙娣€绮夊惛闄勫姂銆傞€欓鍚搁檮鍔戜竴鑸潬铻悎渚�(l谩i)鍚搁檮閲嶉噾灞洟瀛愩€侾ara鍒跺倷鍑�30锛呯殑浜岄啗娣€绮�锛屽苟鐮旂┒瀹冨皪(du矛)涓€绯诲垪閲戝爆闆㈠瓙鐨勮灚鍚堜綔鐢ㄥ﹢銆侹halil鍒跺倷浜嗕竴绯诲垪鍚皑鍩虹殑鏀规€ф穩绮�锛屽苟鐮旂┒瀹冨€戝皪(du矛)閲嶉噾灞洟瀛愮殑铻悎浣滅敤鍚屻€傜櫦(f膩)鐝�(xi脿n)閫欓铻悎鍔戠殑鍚搁檮鑳藉姏闅ㄨ憲姘惈閲忕殑璁婂寲鏈変竴鍊�(g猫)鏈€澶у€硷紟鐒跺悗闁嬪涓嬮檷銆傜浉娉Sl銆丩i绛変汉鐮旂┒浜嗕氦鑱�(li谩n)姘ㄥ熀娣€绮夊皪(du矛)浜嶤u(II)鐨勫惛闄�锛岀櫦(f膩)鐝�(xi脿n)鍚搁檮鏄惛鐔辩殑骞堕伒寰狥reundlich鍚搁檮绛夋韩寮�銆�

2.5銆佹帴鏋濇穩绮夊惛闄勫姂

閫氶亷鎺ユ灊寮曞叆娣€绮夐鏋朵腑甯舵椿鎬у熀鐨勯珮鍒嗗瓙閺堝彲浠ュぇ澶ф彁楂樻穩绮夌殑鍚搁檮閲�銆俍hang绛夎┏绱�(x矛)鐮旂┒浜嗗惈姘ㄥ熀鐨勬按涓嶆憾娣€绮夋帴鏋濆叡鑱氱墿灏�(du矛)浜嶤ufII1鍜孭b(II)鐨勫惛闄勫锛岀爺绌惰〃鏄庡惛闄�2灏忔檪(sh铆)渚垮彲浠ラ仈(d谩)鍒板惛闄勫钩琛�锛屽惛闄勯伒寰狶angmuir鍚搁檮婧紡锛涚暥(d膩ng)?sh霉)鐭稿姠鍙堫灀_(d谩)鍒�60锛呮檪(sh铆)锛庡緸Langmuir鍚搁檮绛夋韩寮忎腑寰楀埌鐨勯＝鍜屽惛闄勯噺灏�(du矛)Pb(II)鐐�2锛�09mmol锛廹锛屽皪(du矛)Cu(II)鐐�2锛�12mmoVg銆侹halil鍒跺倷鍑轰笝鐑吀鎺ユ灊娣€绮�銆傜櫦(f膩)鐝�(xi脿n)瀹冨皪(du矛)浜屽児(ji脿)閲戝爆闆㈠瓙鍏锋湁寰堝ソ鐨勫惛闄勬晥鏋滐紟鍚搁檮閲忛毃钁楃晶鍩虹殑澧炲姞鑰屽澶у懆鍦�(gu贸)骞崇爺绌朵簡姘翠笉婧舵€х晶鍩烘穩绮夋帴鏋濊仛鍚堢墿鍘婚櫎闆婚崓寤㈡按涓瑿r0II)鍜孋d(II)鐨勬晥鏋滃強pH鍊煎皪(du矛)鍘婚櫎鏁堟灉鐨勫奖闊�锛屽苟灏�(du矛)鍏跺惛闄勬(j墨)鐞嗛€�(j矛n)琛屼簡鎺㈣◣銆�