1 鍦嬪収(n猫i)鍗版煋寤�姘磋檿鐞�鍙婂洖鐢ㄧ従(xi脿n)鐙€

鎴戝湅灏�(du矛)鍗版煋寤㈡按鍥炵敤宸叉湁杓冨鐨勭爺绌�锛屽緸鐩墠鐮旂┒鍙婃噳(y墨ng)鐢ㄧ殑鎯呮硜渚嗙湅涓昏鏈変互涓嬬壒榛�(di菐n)锛�

(1)鍥炵敤鎶€琛�(sh霉)澶у铏曚簬瑭﹂(y脿n)鐮旂┒闅庢锛屽鐐哄皬瑭﹀拰涓│锛屽(sh铆)闅涘伐绋嬫噳(y墨ng)鐢ㄨ純灏戯紝涓旀按鐨勫洖鐢ㄧ巼杓冧綆锛屼竴鑸笉瓒呴亷50%锛屼富瑕佸洖鐢ㄤ簬灏�(du矛)姘磋唱(zh矛)瑕佹眰涓嶉珮鐨勫墠閬撳伐搴�锛岀己涔忔湁鍒╀簬鎻愰珮鍥炵敤姘存按璩�(zh矛)鍙婂洖鐢ㄧ巼鐨勯珮鏁堟妧琛�(sh霉)鐨勬帹寤ｆ噳(y墨ng)鐢�銆�

(2)鍥炵敤铏曠悊涓昏鏄皪(du矛)鍗版煋寤㈡按鍦ㄩ仈(d谩)妯�(bi膩o)铏曠悊鐨勫熀绀�(ch菙)涓婇€�(j矛n)涓€姝ラ€�(j矛n)琛岃檿鐞嗭紝閬�(d谩)鍒板洖鐢ㄦ按姘磋唱(zh矛)妯�(bi膩o)婧�(zh菙n)銆傝檿鐞嗗伐钘濅富瑕侀噰鐢ㄦ贩鍑�銆佸惛闄�銆侀亷婵惧拰姘у寲绛夋妧琛�(sh霉)锛屽叾涓皪(du矛)鍘婚櫎楣藉害鍜岀‖搴︾殑闂�(gu膩n)閸垫妧琛�(sh霉)鐮旂┒杓冨皯銆�

(3)鐢变簬鐝�(xi脿n)鏈夋妧琛�(sh霉)姘村钩鐨勯檺鍒�锛屽嵃鏌撳虎姘村ぇ閲忓洖鐢ㄥ皪(du矛)鐢熺敘(ch菐n)鍙婂虎姘磋檿鐞嗙郴绲�(t菕ng)鏈�(hu矛)甯朵締涓€绯诲垪鍟忛锛屽寘鎷湁姗�(j墨)姹℃煋鐗╁拰鐒℃(j墨)楣界殑绌嶇疮銆傜洰鍓嶅皪(du矛)寤㈡按闀锋湡鍥炵敤鐨勬按璩�(zh矛)鍟忛鍙婂皪(du矛)姘磋檿鐞嗙郴绲�(t菕ng)鐨勫奖闊跨爺绌朵笉澶氾紝鐗瑰垾鏄劇姗�(j墨)楣界殑绌嶇疮鍟忛鍩烘湰娌掓湁娑夊強銆�

2 鍗版煋寤㈡按娣卞害铏曠悊鍥炵敤鎶€琛�(sh霉)鍙婂伐钘�

鍗版煋寤㈡按娣卞害铏曠悊涓昏灏�(du矛)甯歌(gu墨)浜岀礆(j铆)铏曠悊绯荤当(t菕ng)鍑烘按閫�(j矛n)琛岃檿鐞�锛屽幓闄ょ殑姹℃煋鐗╀富瑕佹槸鑹插害銆丆OD 鍜岄菇搴�(闆诲皫(d菐o)鐜�)绛夛紝浣垮嚭姘存按璩�(zh矛)婊胯冻鐢熺敘(ch菐n)宸ヨ棟瑕佹眰銆傚嵃鏌撳伐钘濆拰鐢�(ch菐n)鍝佽唱(zh矛)閲忚姹備笉鍚�锛屽皪(du矛)鍥炵敤姘寸殑姘磋唱(zh矛)瑕佹眰涔熶笉鍚�銆傚洜姝�锛屾垜鍦嬪皻娌掓湁绲�(t菕ng)涓€鐨勫嵃鏌撳虎姘村洖鐢ㄦ按姘磋唱(zh矛)妯�(bi膩o)婧�(zh菙n)銆傛牴鎿�(j霉)琛屾キ(y猫)缍�(j墨ng)椹�(y脿n)锛屾按璩�(zh矛)鎸囨(bi膩o)閮藉繀闋堟帶鍒跺湪鐢ㄦ按鎸囨(bi膩o)涔嬪収(n猫i)銆傚洜姝�锛岀础绻斿嵃鏌撴キ(y猫)灏�(du矛)鍥炵敤姘存按璩�(zh矛)鐨勮姹傞仩(yu菐n)閬�(yu菐n)楂樹簬鍩庡競鐢熸椿闆滅敤姘寸殑姘磋唱(zh矛)瑕佹眰銆�

2.1 娣卞害铏曠悊鍠厓鎶€琛�(sh霉)

2.1.1 鍚搁檮铏曠悊鎶€琛�(sh霉)

灏囧虎姘撮€氶亷鐢卞惛闄勫姂绲勬垚鐨勬烤搴�锛屾薄鏌撶墿璩�(zh矛)琚惛闄勫湪澶氬瓟鐗╄唱(zh矛)琛ㄩ潰涓婃垨琚亷婵鹃櫎鍘�銆傛椿鎬х偔鏄嵃鏌撳虎姘存繁搴﹁檿鐞嗕腑鏈€甯哥敤鐨勫惛闄勫姂锛屽叾寰瓟澶氾紝姣旇〃闈㈢⿳鍙珮閬�(d谩)500锝�600 m2/g锛屽叿鏈夊緢寮�(qi谩ng)鐨勫惛闄勮劔鑹叉€ц兘锛岀壒鍒ラ仼鍚堢浉灏�(du矛)鍒嗗瓙璩�(zh矛)閲忓皬浜�400 鐨勬按婧舵€ф煋鏂欑殑鑴壊鍚搁檮銆備絾娲绘€х偔灏�(du矛)鐤忔按鎬ф煋鏂欏惛闄勬晥鏋滆純宸�锛屽叾鍐嶇敓涔熸瘮杓冨京(f霉)闆滀笖璨�(f猫i)鐢ㄦ槀璨�锛岄檺鍒朵簡鍚搁檮娉曞湪鍗版煋寤㈡按娣卞害铏曠悊涓殑鎳�(y墨ng)鐢ㄣ€傚ぉ鐒剁う鐗╁楂樺逗鍦�銆佺钘诲湡銆佹椿鎬х櫧鍦熶互鍙婄叅绮夌瓑涔熷叿鏈夎純楂樼殑鍚搁檮鎬ц兘锛屽湪鍗版煋寤㈡按鐨勬繁搴﹁檿鐞嗕腑涔熸湁浣跨敤銆傚彟澶栵紝鏉庤挋鑻辩瓑銆�2銆� 鐮旂┒浜嗗埄鐢ㄩ潚闇夎弻灏�(du矛)鍗版煋寤㈡按閫�(j矛n)琛屽惛闄勮檿鐞�锛岀祼(ji茅)鏋滅櫦(f膩)鐝�(xi脿n)锛� 鍏跺皪(du矛)榛戣壊鍜岀磪鑹叉煋娴村虎姘寸殑鑹插害鍏锋湁杓冨ソ鐨勮檿鐞嗘晥鏋�锛屽幓闄ょ巼閬�(d谩)鍒颁簡98.0%鍜�74.5%锛岀偤鍚搁檮娉曠殑鐧�(f膩)灞曟彁渚涗簡鏂扮殑閬告搰銆傚惛闄勬硶闆栫劧瑕嬫晥蹇�锛屼絾鏄娇鐢ㄥ悗鐨勫惛闄勫姂鍐嶇敓姣旇純鍥伴洠锛屽鏋滀笉閫�(j矛n)琛屽洖鏀跺啀鐢熷墖瀹规槗鐢�(ch菐n)鐢熶簩娆℃薄鏌�銆傚洜姝わ紝鐮旂櫦(f膩)鏂板瀷楂樻晥涓旀槗鍐嶇敓鐨勫惛闄勫姂鏄暥(d膩ng)鍓嶅惛闄勬柟娉曠殑鐮旂┒鐧�(f膩)灞曟柟鍚�銆�

2.1.2 鑶滃垎闆㈡妧琛�(sh霉)

鑶滃皪(du矛)涓嶅悓鐗╄唱(zh矛)鍏锋湁閫忛亷鎬у樊鐣�锛岃啘鍒嗛洟鎶€琛�(sh霉)灏辨槸鍒╃敤鑶滅殑閫欑ó鐗规€�锛屽湪涓€瀹氱殑鍌宠唱(zh矛)鎺ㄥ嫊(d貌ng)鍔涗笅锛屽皪(du矛)娣峰悎鐗╅€�(j矛n)琛屽垎闆㈢殑鏂规硶銆傚嵃鏌撳虎姘存繁搴﹁檿鐞嗘墍鐢ㄧ殑鑶滃垎闆㈡妧琛�(sh霉)涓昏鏈夊井婵�(MF)銆佽秴婵�(UF)銆佺磵婵�(NF)鍜屽弽婊查€�(RO)銆侻F 鍜孶F 甯镐綔鐐篘F 鍜孯O 鐨勯爯(y霉)铏曠悊; UF 鑳藉垎闆㈠ぇ鍒嗗瓙鏈夋(j墨)鐗┿€佽啝楂�銆佹嚫娴浐楂�;NF 鑳藉(sh铆)鐝�(xi脿n)鑴菇鑸囨績绺殑鍚屾檪(sh铆)閫�(j矛n)琛�;RO 鑳藉幓闄ゅ彲婧舵€ч噾灞菇銆佹湁姗�(j墨)鐗�銆佽啝绮掔瓑骞舵埅鐣欐墍鏈夐洟瀛�銆傞槷鎱ф晱绛夈€�3銆曢噰鐢║F+RO 宸ヨ棟灏�(du矛)娴欐睙鏌愬嵃鏌撳粻寤㈡按鐢熷寲铏曠悊鍚庣殑鍑烘按閫�(j矛n)琛岃檿鐞�锛岃啘绯荤当(t菕ng)閫�(j矛n)姘碈OD 100~350 mg/L锛岃壊搴�180 鍊�锛岄浕灏�(d菐o)鐜�800~1 350 渭S/cm銆傝啘绯荤当(t菕ng)铏曠悊鍚庡嚭姘碈OD<10 mg/L锛岃壊搴�1~2 鍊�锛岄浕灏�(d菐o)鐜�<30 渭S/cm銆� Xujie Lu 绛夈€�4銆曢噰鐢ㄧ敓鐗╂烤姹犵祼(ji茅)鍚堣啘鍒嗛洟鐨勬柟娉曪紝鐣�(d膩ng)閫�(j矛n)姘碈OD 鐐�150~450 mg/L 鏅�(sh铆)锛屽嚭姘碈OD 闄嶅埌50 mg/L 浠ヤ笅锛屽幓闄ょ巼楂橀仈(d谩)91%锛屼笖鑹插害銆佹縼搴︺€侀惖閷虫績搴︾殑鍘婚櫎鏁堟灉閮介潪甯稿ソ銆�

鑶滃垎闆㈡妧琛�(sh霉)鐨勫劒(y艒u)鍕�(sh矛)鐐猴細 鍏朵笉鍍呰兘鍘婚櫎姘翠腑娈樹綑鐨勬湁姗�(j墨)鐗�锛岄檷浣庤壊搴�锛岄倓鑳借劔闄ょ劇姗�(j墨)楣介锛岄槻姝㈢郴绲�(t菕ng)涓劇姗�(j墨)楣界殑绌嶇疮锛屾槸鍗版煋寤㈡按娣卞害铏曠悊涓サ鍏峰墠鏅殑涓€闋�(xi脿ng)鎶€琛�(sh霉)銆傜劧鑰�锛岃啘铏曠悊宸ヨ棟鐨勬垚鏈純楂�锛屼笖鑶滅祫浠舵槗琚薄鏌撹€岀府鐭叾浣跨敤澹藉懡銆傚彧鏈夐€氶亷鎺у埗骞堕檷浣庤啘姹℃煋渚嗗欢闀疯啘澹藉懡锛屽緸鑰岄檷浣庢垚鏈�锛岃啘鍒嗛洟鎶€琛�(sh霉)鍦ㄥ嵃鏌撳虎姘存繁搴﹁檿鐞嗕腑鎵嶆渻(hu矛)寰楀埌鏇村姞寤ｆ硾鐨勬噳(y墨ng)鐢ㄣ€�

2.1.3 楂樼礆(j铆)姘у寲娣卞害铏曠悊鎶€琛�(sh霉)

(1)鍖栧(xu茅)姘у寲鎶€琛�(sh霉)銆傚湪鍗版煋寤㈡按娣卞害铏曠悊涓�锛孫3 鍜孎enton 瑭﹀姂鏄瘮杓冨父鐢ㄧ殑姘у寲鍔�銆侽3 鍏锋湁杓冨挤(qi谩ng)鐨勮劔鑹蹭綔鐢�锛岄洊鐒跺皪(du矛)COD 鐨勫幓闄ゆ晥鏋滃緢灏�锛屼絾鏄彲浠ユ敼璁婂虎姘寸殑B/C锛屽緸鑰屾彁楂樺虎姘寸殑鍙敓鍖栨€�銆傜洤瀵у窛绛夈€�5銆曢噰鐢∣3 姘у寲灏�(du矛)鍗版煋寤㈡按閫�(j矛n)琛岃檿鐞�锛岀祼(ji茅)鏋滅櫦(f膩)鐝�(xi脿n)锛� COD 鐨勫幓闄ょ巼鐐�72%锛岃€岃壊搴﹂檷浣庝簡94%銆傞儹鍙捣绛夈€�6銆曠爺绌朵簡O3 灏�(du矛)鑹插害鍘婚櫎鍜孊/C 鐨勫奖闊�锛岀櫦(f膩)鐝�(xi脿n)鑷哀鐨勬姇鍔犻噺鐐�15 mg/L 宸﹀彸鏅�(sh铆)锛岃壊搴︾殑鍘婚櫎鐜囧彲浠ラ仈(d谩)鍒�70%锛孊/C 涔熸彁楂樹簡涓€鍊嶅銆侽3 姘у寲鐨勪富瑕佸劒(y艒u)榛�(di菐n)鏄ō(sh猫)鍌欑啊鍠穵婀�銆佸崰鍦伴潰绌嶅皬銆佸鏄撳(sh铆)鐝�(xi脿n)鑷嫊(d貌ng)鍖栨帶鍒�;涓昏缂洪粸(di菐n)鏄檿鐞嗘垚鏈珮锛屼笉閬╁悎澶ф祦閲忓虎姘寸殑铏曠悊銆�

Fenton 瑭﹀姂鏄敱H2O2 鍜孎e2+寰�(f霉)鍚堣€屾垚鐨勬哀鍖栧姂锛屽湪閰告€ф浠朵笅鐢�(ch菐n)鐢熺殑路OH 鍏锋湁妤靛挤(qi谩ng)鐨勬哀鍖栦綔鐢紝鐗瑰垾閬╁悎铏曠悊鎴愬垎姣旇純寰�(f霉)闆滅殑鏌撴枡寤㈡按銆傚鑸堣彲绛夈€�7銆曞埄鐢‵enton 瑭﹀姂灏�(du矛)鍗版煋寤㈡按閫�(j矛n)琛屾繁搴﹁檿鐞�锛岀祼(ji茅)鏋滅櫦(f膩)鐝�(xi脿n)锛歱H 2~3锛孒2O2 鐢ㄩ噺3.2 mL/L锛岄惖鐐珨绌嶆瘮 1鈭�1锛屽弽鎳�(y墨ng)鏅�(sh铆)闁�90 min 鏅�(sh铆)锛屽嚭姘碈OD 鍘婚櫎90%浠ヤ笂锛岃壊搴﹂檷浣�99%锛岄菇搴﹂檷浣�64%锛屽洖鐢ㄦ按姘磋唱(zh矛)鎸囨(bi膩o)鍧囬仈(d谩)鍒颁簡鍥炵敤瑕佹眰銆傚彶绱呴绛夈€�8銆曚篃灏�(du矛)Fenton 瑭﹀姂铏曠悊鍗版煋寤㈡按閫�(j矛n)琛屼簡鐮旂┒锛岀嵅寰椾簡椤炰技鐨勭祼(ji茅)鏋�銆侳enton 姘у寲灏�(du矛)COD 鍜岃壊搴﹀叿鏈夎純寮�(qi谩ng)鐨勫幓闄よ兘鍔�锛屼絾鏄惖闆㈠瓙鐨勫瓨鍦ㄥ彲鑳芥渻(hu矛)褰遍熆姘寸殑椤忚壊锛岃€屼笖鍙嶆噳(y墨ng)鐨刾H 杓冧綆锛屽彲鑳藉皪(du矛)鍏朵粬铏曠悊宸ュ簭鏈夊奖闊�銆�

(2)鍏夊偓鍖栨哀鍖栨妧琛�(sh霉)銆傚埄鐢ㄥ挤(qi谩ng)姘у寲鍔戝湪UV 杓诲皠涓嬬敘(ch菐n)鐢熷叿鏈夊挤(qi谩ng)姘у寲鑳藉姏鐨劼稯H 渚嗚檿鐞嗗虎姘�锛屽叿鏈変綆鑳借€椼€佺劇浜屾姹℃煋銆佹哀鍖栧竟搴曠瓑鍎�(y艒u)榛�(di菐n)锛屾渶甯哥敤鐨勬湁 UV/Fenton銆乁V/O3銆乁V/H2O2 绛夈€傚厜鍌寲鐮旂┒杓冨鐨勯倓鏈変互鍏夋晱鍖栧崐灏�(d菐o)楂旂偤鍌寲鍔�锛屽叾涓璗iO2 鍏夊偓鍖栧姂鎳�(y墨ng)鐢ㄦ渶寤ｏ紝涓旇檿鐞嗘晥鏋滄渶濂�銆俆iO2 鍦ㄥ厜杓诲皠涓嬶紝鍏跺児(ji脿)甯朵笂鏈�(hu矛)鐢�(ch菐n)鐢熼浕瀛愮┖绌�(h+)灏�(du矛)锛孴iO2 琛ㄩ潰鍚搁檮鐨勬湁姗�(j墨)鐗╄鍏锋湁寮�(qi谩ng)姘у寲鎬х殑h+娲诲寲銆佹哀鍖栬€岄檷瑙�銆傞Ξ楹楀绛夈€�9銆曢噰鐢ㄤ簡TiO2/娲绘€х偔璨�(f霉)杓夐珨绯诲皪(du矛)鏌愬嵃鏌撳粻鐨勪簩绱�(j铆)铏曠悊鍑烘按閫�(j矛n)琛岃檿鐞�锛岄€�(j矛n)姘碈OD 鍦�300 mg/L 宸﹀彸锛屽湪鏈€浣冲弽鎳�(y墨ng)姊濅欢涓�锛屽嚭姘碈OD 闄嶅埌50 mg/L锛岃壊搴﹂檷鐐� 2 鍊�锛岀爺绌惰〃鏄庯細鍒╃敤娲绘€х偔鐨勫惛闄勬€ц兘锛屾湁鍔╀簬瑙ｆ焙TiO2 鐨勬祦澶便€佸垎闆㈠拰鍥炴敹鍟忛锛屾彁楂樺厜鍌寲鍔戠殑铏曠悊鏁堟灉銆備絾寤㈡按鏈韩鐨勯€忓厜鎬у拰鍏夊埄鐢ㄧ巼鍒剁磩钁楀厜鍌寲鎶€琛�(sh霉)鍦ㄥ虎姘磋檿鐞嗗伐妤�(y猫)涓殑鎳�(y墨ng)鐢�銆�

(3)闆诲寲瀛�(xu茅)姘у寲鎶€琛�(sh霉)銆傚湪澶栧姞闆诲牬(ch菐ng)浣滅敤涓�锛屽湪鐗瑰畾鍙嶆噳(y墨ng)鍣ㄥ収(n猫i)锛岄€氶亷涓€瀹氬寲瀛�(xu茅)鍙嶆噳(y墨ng)銆侀浕鍖栧(xu茅)閬庣▼鎴栫墿鐞嗛亷绋�锛岀敘(ch菐n)鐢熷ぇ閲忕殑鑷敱鍩�锛屽埄鐢ㄨ嚜鐢卞熀鐨勫挤(qi谩ng)姘у寲鎬у皪(du矛)寤㈡按涓殑姹℃煋鐗╅€�(j矛n)琛岄檷瑙ｇ殑閬庣▼銆傞浕鍖栧(xu茅)鎶€琛�(sh霉)鍏锋湁鏄撴帶鍒�銆佺劇姹℃煋鎴栧皯姹℃煋銆侀珮搴﹂潏娲荤瓑鐗归粸(di菐n)銆�

M. Kennedy銆�10銆曟寚鍑洪浕鍖栧(xu茅)鏂规硶灏�(du矛)鍗版煋寤㈡按鐨勮劔鑹查潪甯告湁鏁�锛岀暥(d膩ng)闆诲寲瀛�(xu茅)鍙嶆噳(y墨ng)鍣ㄤ腑寤㈡按涓绘祦鍗€(q奴)Fe2+璩�(zh矛)閲忔績搴︾偤200~500 mg/L 鏅�(sh铆)锛岃壊搴﹀幓闄ょ巼閬�(d谩)鍒�90%~98%锛孋OD 鍜孊OD 鍘婚櫎鐜囧垎鍒ラ仈(d谩)鍒�50%鍜�70%銆備絾閫欑ó鍙憾鎬ч浕妤垫哀鍖栨硶鐨勯浕妤垫秷鑰楅亷澶�锛屾晠鏂板瀷闆绘サ鐨勯枊鐧�(f膩)灏辨垚鐐虹爺绌剁殑鐔遍粸(di菐n)涔嬩竴銆傝硤閲戝钩绛夈€�11銆曞埄鐢ㄦ椿鎬х偔绾栫董鑸囬惖鐨勫京(f霉)鍚堥浕妤甸檷瑙ｅ绋ā鎿嵃鏌撳虎姘�锛屽彇寰椾簡杓冨ソ鐨勭祼(ji茅)鏋�銆傞浄闄芥槑绛夈€�12銆曚互PbO2/Ti 鐐洪櫧妤佃檿鐞嗘ā鎿嵃鏌撳虎姘�锛岃壊搴﹀拰COD 鍘婚櫎鐜囨渶楂樺彲閬�(d谩) 99.5%鍜�78.6%銆�

2.1.4 楂樻晥鐢熺墿铏曠悊鎶€琛�(sh霉)

鍗版煋寤㈡按浜岀礆(j铆)鍑烘按姹℃煋鐗╁彲鐢熷寲鎬т笉楂�锛岀敓鐗╅檷瑙ｆ湁涓€瀹氶洠搴�锛岀敓鐗╂硶鐨勯噸榛�(di菐n)鍦ㄤ簬闁嬬櫦(f膩)寮�(qi谩ng)鍖栫敓鐗╂妧琛�(sh霉)鐨勬柊鍨嬬敓鐗╁弽鎳�(y墨ng)鍣�锛屼互閫�(j矛n)涓€姝ュ幓闄OD 鍜岃壊搴�銆�

(1)鏇濇埃鐢熺墿婵炬睜(BAF)銆傚嵃鏌撳虎姘寸稉(j墨ng)浜岀礆(j铆)鐢熷寲铏曠悊鍚�锛屾按涓瑿OD 鍙夿OD 鐩稿皪(du矛)杓冧綆锛屾洕姘ｇ敓鐗╂烤姹犲～鏂欎笂鐢熼暦鐨勮钵鐕熼(y菐ng)寰敓鐗╁鍋囧柈鑳炶弻銆佽娊瀛㈡】鑿岀瓑锛屾瘮琛ㄩ潰绌嶈純澶э紝灏�(du矛)寤㈡按涓殑鏈夋(j墨)鐗╂湁杓冨挤(qi谩ng)鐨勮Κ鍜屽姏銆傚懆閶掋€�13銆曠爺绌朵簡BAF 铏曠悊鍗版煋寤㈡按鐨勪簩绱�(j铆)鍑烘按锛屾按瑙ｉ吀鍖�+濂芥哀宸ヨ棟鍚庡鍔燘AF 娣卞害铏曠悊宸ヨ棟锛岀暥(d膩ng)閫�(j矛n)姘碈OD<200 mg/L锛屾按鍔涜矤(f霉)鑽�1.0锝�2.0 m3/(m2路h)锛屾埃姘存瘮鐐�(2锝�3)鈭�1 鏅�(sh铆)锛屽嚭姘碈OD 鍘婚櫎鐜囧湪50%浠ヤ笂锛岄仈(d谩)鍒颁竴绱�(j铆)鎺掓斁妯�(bi膩o)婧�(zh菙n)銆傛洕姘ｇ敓鐗╂烤姹犱腑鐢熺墿婵冨害鍜屾湁姗�(j墨)璨�(f霉)鑽烽珮锛岃檿鐞嗘晥鏋滅┅(w臎n)瀹氾紝鍑烘按姘磋唱(zh矛)濂�銆傛烤姹犱腑鐨勬烤鏂欑矑寰戣秺灏忚檿鐞嗘晥鏋滆秺濂斤紝浣嗘槸灏忕矑寰戝張鏈�(hu矛)浣垮伐浣滃懆鏈熻畩鐭�锛屾烤鏂欎笉鏄撴竻娲�锛岀浉鎳�(y墨ng)鐨勫弽娌栨礂姘撮噺涔熸渻(hu矛)澧炲姞銆傚洜姝ら伕鐢ㄥ悎閬╃殑婵炬枡绮掑緫鏄厖鍒嗙櫦(f膩)鎻洕姘ｇ敓鐗╂烤姹犲姛鑳界殑闂�(gu膩n)閸�銆�

(2)绉诲嫊(d貌ng)搴婄敓鐗╄啘鍙嶆噳(y墨ng)鍣�(MBBR)銆侻BBR 鏄竴绋柊鍨嬬殑鐢熺墿鑶滃弽鎳�(y墨ng)鍣�銆傚井鐢熺墿鍦ㄥ弽鎳�(y墨ng)鍣ㄥ収(n猫i)鐨勫～鏂欎笂瀵岄泦锛屽～鏂欐嚫娴簬鍙嶆噳(y墨ng)鍣ㄥ収(n猫i)骞堕毃钁楁贩鍚堟恫娴佸嫊(d貌ng)锛屽洜姝ゆ埃銆佹按銆佸～鏂欎笁鑰呰兘澶犲湪鍙嶆噳(y墨ng)鍣ㄥ収(n猫i)鍏呭垎鎺ヨЦ锛屾哀鐨勫埄鐢ㄧ巼鍜屾湁姗�(j墨)姹℃煋鐗╃殑鍌宠唱(zh矛)鏁堢巼楂�锛屼笖鐢熺墿鑶滅殑娲绘€ц純楂�锛岃€佸寲鐨勭敓鐗╄啘鏄撳緸濉枡琛ㄩ潰鑴惤銆侻BBR 閭勫叿鏈変笉闇€瑕佸弽娌栨礂銆佹姉娌栨搳璨�(f霉)鑽峰挤(qi谩ng)銆佸嚭姘存按璩�(zh矛)绌�(w臎n)瀹氱瓑鍎�(y艒u)榛�(di菐n)銆�14銆�銆�

鐩墠闂�(gu膩n)浜庣敤MBBR 宸ヨ棟铏曠悊鍗版煋寤㈡按鐨勭爺绌朵笉澶�銆傞湇妗冩銆�15銆曠櫦(f膩)鐝�(xi脿n)MBBR 娣卞害铏曠悊鍗版煋寤㈡按鏅�(sh铆)灏�(du矛) COD 鍙婃皑姘叐闋�(xi脿ng)鎸囨(bi膩o)鏈夎壇濂界殑鍘婚櫎鏁堟灉銆傞€�(j矛n)姘碈OD 鐢�200 mg/L 宸﹀彸闄嶅埌50 mg/L 浠ヤ笅锛屾皑姘敱10 mg/L 闄嶅埌2 mg/L 浠ヤ笅锛屼絾鑹插害鍘婚櫎鐜囧儏鐐�25%銆�

鍗版煋寤㈡按涓湁姗�(j墨)姹℃煋鐗╁搧绋純澶氾紝鐢熺墿濉枡涓婄殑澶氳弻绋珨绯绘湁杓冨ぇ鐨勯檷瑙ｈ兘鍔�锛屾墍浠BBR 浣滅偤娣卞害铏曠悊宸ヨ棟灏�(du矛)鏈夋(j墨)鐗╂績搴﹁純浣庣殑浜岀礆(j铆)鐢熷寲铏曠悊鍑烘按鍏锋湁寰堝ぇ鐨勫劒(y艒u)鍕�(sh矛)銆傛湭渚嗗彲浠ュ皣MBBR 鍦ㄥ嵃鏌撳虎姘存繁搴﹁檿鐞嗕腑鐨勭爺绌跺拰鎳�(y墨ng)鐢ㄤ綔鐐轰竴鍊�(g猫)鐧�(f膩)灞曟柟鍚�銆�

(3)鑶滅敓鐗╁弽鎳�(y墨ng)鍣�(MBR)銆傝啘鐢熺墿鍙嶆噳(y墨ng)鍣ㄩ泦鑶滃垎闆㈣垏鐢熺墿闄嶈В浜庝竴楂�锛屽彲鍘婚櫎寤㈡按涓ぇ閮ㄥ垎娈樹綑鐨凜OD銆佽壊搴﹀拰鎵€鏈夌殑SS銆傝€屽悗閫氶亷NF(RO)宸ヨ棟閫�(j矛n)涓€姝ヨ檿鐞�锛屽幓闄ゅぇ閮ㄥ垎楣藉害锛屽嚭姘存按璩�(zh矛)涓€鑸兘閬�(d谩)鍒板洖鐢ㄦ按瑕佹眰銆傛埓鑸掔瓑銆�16銆曚互鍥炵敤鐐虹洰鐨勶紝閲囩敤鐢卞ソ姘у弽鎳�(y墨ng)鍣ㄥ拰瓒呮烤鑶滅祫鎴愬缃紡MBR 绲�(ji茅)鍚堢磵婵捐啘铏曠悊鍗版煋寤㈡按锛岀祼(ji茅)鏋滆〃鏄庯細绯荤当(t菕ng)COD銆佽壊搴﹀拰婵佸害鐨勫幓闄ょ巼鍧囬仈(d谩)鍒�99%锛岄浕灏�(d菐o)鐜囧幓闄ょ巼97%銆侾.Schoeberl 绛夈€�17銆� 鍏堥噰鐢∕BR 鍜孨F 绲�(ji茅)鍚堣檿鐞嗗嵃鏌撳虎姘�锛屽嚭姘存按璩�(zh矛)鍏ㄩ儴婊胯冻鍥炵敤姘存寚妯�(bi膩o)锛屼絾鏄€冩叜鍒版妧琛�(sh霉)闆ｅ害鍜岄珮椤嶇殑缍�(j墨ng)婵�(j矛)鎴愭湰锛岃€屽悗鐢║F 浠ｆ浛NF 鍚屾ǎ鍙栧緱杓冨ソ鐨勬晥鏋�銆侻BR 鐨勫劒(y艒u)榛�(di菐n)鍦ㄤ簬宸ヨ棟娴佺▼鐭€佸崰鍦伴潰绌嶅皯銆佸嚭姘存按璩�(zh矛)绌�(w臎n)瀹�;缂洪粸(di菐n)鍜岃啘鍒嗛洟鎶€琛�(sh霉)椤炰技锛屼富瑕佹槸鑶滄薄鏌撳皫(d菐o)鑷寸殑鑶滃＝鍛界煭銆佹垚鏈珮鍜岄浕鑰楅珮銆�

2.2 鍗版煋寤㈡按娣卞害铏曠悊鍥炵敤闆嗘垚宸ヨ棟

2.2.1 鍌崇当(t菕ng)鎶€琛�(sh霉)绲勫悎宸ヨ棟

鐢变簬鍗版煋寤㈡按姘磋唱(zh矛)寰�(f霉)闆滐紝寤㈡按鍥炵敤鍙潬鍠竴鎶€琛�(sh霉)闆ｄ互瀵�(sh铆)鐝�(xi脿n)锛屽洜姝ら渶瑕佸皣鍚勭ó鏂规硶鏈夋(j墨)绲�(ji茅)鍚堣捣渚�锛岄噰鐢ㄧ祫鍚堝伐钘濋€�(j矛n)琛岀稖鍚堣檿鐞�銆俋iaojun Wang 绛夈€�18銆曢噰鐢ㄨ嚟姘ц伅(li谩n)鍚堢敓鐗╂硶铏曠悊鍗版煋寤㈡按锛岃嚟姘ф哀鍖栧悗寤㈡按B/C 鐢�0.18 鎻愰珮鍒�0.36锛孋OD 鍜岃壊搴︾殑鍘婚櫎鐜囦篃閮芥湁涓€瀹氱殑鎻愰珮銆傞粌鐟炴晱绛夈€�19銆曢噰鐢ㄦ贩鍑濊劔鑹测€旀洕姘ｇ敓鐗╂烤姹犫€旈洟瀛愪氦鎻涚祫鍚堝伐钘濊檿鐞嗛嚌绻旀甯冩煋鑹插虎姘达紝鍑烘按鑹插害鍘婚櫎鑷�10 鍊嶄互涓�锛孋OD<20 mg/L锛孲S 浣庝簬2 mg/L锛屾縼搴︿綆浜�3 NTU銆傞儹鍙捣绛夈€�6銆曠爺绌朵簡O3 姘у寲鍜岀敓鐗╂烤姹犵祫鍚堝伐钘濊檿鐞嗗嵃鏌撳虎姘寸殑鏁堟灉锛岀櫦(f膩)鐝�(xi脿n) O3-鐢熺墿婵炬睜绲勫悎鎶€琛�(sh霉)寰堝ソ鍦扮櫦(f膩)鎻簡鍖栧(xu茅)姘у寲銆佸惛闄勫拰鐢熺墿闄嶈В鐨勫崝(xi茅)鍚屼綔鐢�锛屼笖鍏锋湁閬�(y霉n)琛屾垚鏈綆銆佷笉鐢�(ch菐n)鐢熸績绺恫鍜屽墿浣欐薄娉ュ皯绛夊劒(y艒u)榛�(di菐n)銆傚柈涓€鎶€琛�(sh霉)鐢ㄤ簬娣卞害铏曠悊锛岄洠浠ュ悓鏅�(sh铆)瑙ｆ焙鑴壊銆侀檷COD 鍜岄櫎楣界瓑鍟忛锛屽皣鍚勭ó鍠竴鎶€琛�(sh霉)閫�(j矛n)琛屾湁姗�(j墨)绲�(ji茅)鍚�锛岃兘寰楀埌杓冨ソ鐨勮檿鐞嗘晥鏋�锛岄倓鑳戒繚璀夊厖鍒嗙櫦(f膩)鎻悇鎶€琛�(sh霉)鐨勫劒(y艒u)鍕�(sh矛)锛屾彁楂樻薄鏌撶墿鍘婚櫎鐜�銆�

2.2.2 鑶滄妧琛�(sh霉)鑸囧偝绲�(t菕ng)鎶€琛�(sh霉)鐨勯泦鎴愬伐钘�

鍗版煋寤㈡按鎴愬垎寰�(f霉)闆�锛屽閬哥敤鑶滄妧琛�(sh霉)铏曠悊鍗版煋寤㈡按锛屽繀闋堥伕鎿囧悎閬╃殑鍓嶈檿鐞嗗伐钘濅締闃绘寤㈡按涓殑鑶犻珨銆佹湁姗�(j墨)璩�(zh矛)銆佹嚫娴墿绛夊皪(du矛)鑶滈€犳垚姹℃煋銆侫. Bes-Pi谩 绛夈€�20銆� 閲囩敤O3 鑸嘚F 绲�(ji茅)鍚堢殑宸ヨ棟灏�(du矛)缍�(j墨ng)鐢熷寲铏曠悊鍚庣殑鍗版煋寤㈡按閫�(j矛n)琛岃檿鐞嗗洖鐢�锛屼互O(sh猫)3 渚嗘哀鍖栧紩璧疯啘姹℃煋鐨勬湁姗�(j墨)鐗╄唱(zh矛)锛屽嚭姘寸殑鍚勯爡(xi脿ng)鎸囨(bi膩o)鍙互閬�(d谩)鍒板洖鐢ㄦ(bi膩o)婧�(zh菙n)銆侻. Marcucci 绛夈€�21銆曢嚌灏�(du矛)鐢熺敘(ch菐n)杌婇枔鐨勭洿鎺掑虎姘撮€�(j矛n)琛岀墿鍖栭爯(y霉)铏曠悊鍚�锛屽埄鐢ㄧ诞鍑濇矇娣€銆丱3 姘у寲鍜孶F 閫�(j矛n)琛屽悗绾�(x霉)娣卞害铏曠悊锛屾暣鍊�(g猫)宸ヨ棟閬庣▼鑹插害鍘婚櫎鐜囩偤93%锛孋OD 鍘婚櫎鐜囩偤66%銆傝啘鐨勬薄鏌撳晱椤岄檺鍒朵簡鑶滄妧琛�(sh霉)鍦ㄥ嵃鏌撳虎姘磋檿鐞嗕腑鐨勬噳(y墨ng)鐢�锛岄噰鐢∣3 姘у寲绛夐爯(y霉)铏曠悊鎵嬫渚嗘帶鍒惰啘姹℃煋锛屽緸鑰屽鍔犺啘鐨勪娇鐢ㄥ＝鍛斤紝闄嶄綆铏曠悊鎴愭湰锛屾槸鏈締鍗版煋寤㈡按娣卞害铏曠悊鐨勪竴澶ц定鍕�(sh矛)銆�

2.2.3 闆嗘垚鑶滆檿鐞嗗洖鐢ㄥ伐钘�

鍦嬪寰堝鐮旂┒璀夋槑锛屽皣涓嶅悓鐨勮啘鍒嗛洟鎶€琛�(sh霉)绲�(ji茅)鍚�锛屾(g貌u)鎴愰泦鎴愯啘宸ヨ棟锛屾槸鍗版煋寤㈡按娣卞害铏曠悊鐨勪竴鍊�(g猫)閲嶈鏂瑰悜銆侻. Marcucci 绛夈€�21銆曞皪(du矛)缍�(j墨ng)鐮傛烤銆乁F 铏曠悊鍚庣殑鍗版煋寤㈡按锛屽啀鐢∟F 鎴朢O 閫�(j矛n)琛屾繁搴﹁檿鐞�銆傚(sh铆)椹�(y脿n)璀夋槑锛歂F 鎴朢O 浣滅偤娣卞害铏曠悊鏂规鏄彲琛岀殑锛孯O 鍑烘按鍙洖鐢ㄤ簬浠讳綍鍗版煋宸ュ簭锛孨F 鍦ㄨ劔楣藉拰鍘婚櫎绀︾墿璩�(zh矛)鏂归潰涓嶅 RO锛屼絾閬�(y霉n)琛屾垚鏈綆浜嶳O銆�

娴欐睙鑷崇編鐠�(hu谩n)澧冮枊鐧�(f膩)浜嗏€滆嚟姘у偓鍖栨哀鍖�+CMF+ RO鈥濇繁搴﹁檿鐞嗗伐钘�锛屽苟寤烘垚1 500 m3/d 鐨勫嵃鏌撳虎姘磋啘娉曡檿鐞嗗洖鐢ㄧず鑼冨伐绋�銆侽3 鍌寲姘у寲绯荤当(t菕ng)涓昏鐢ㄤ簬鍘婚櫎姘翠腑闆ｇ敓鍖栭檷瑙ｆ湁姗�(j墨)姹℃煋鐗╃殑COD 鍜岃壊搴�锛屽幓闄ょ巼鍒嗗垾鍙仈(d谩)30%~40%鍜�90%浠ヤ笂銆傝嚟姘у偓鍖栨哀鍖栧嚭姘撮€�(j矛n)鍏ラ€ｇ簩(x霉)瓒呭井婵�(CMF)绯荤当(t菕ng)锛屽嚭姘存按璩�(zh矛)绌�(w臎n)瀹�锛孋OD 绌�(w臎n)瀹氬湪40 mg/L 宸﹀彸锛屾縼搴�<0.4 NTU锛屾薄鏌撴寚鏁�(sh霉)(SDI)<3銆傚啀缍�(j墨ng)鍙嶆徊閫忚檿鐞嗗悗锛屽嚭姘碈OD<10 mg/L锛岄浕灏�(d菐o)鐜�<10.5 渭S/cm锛孲S 鍜岃壊搴﹀潎鐐�0锛屾豢瓒虫帹钖︾殑楂樼礆(j铆)鍥炵敤姘存按璩�(zh矛)妯�(bi膩o)婧�(zh菙n)銆傛暣鍊�(g猫)宸ヨ棟閫氶亷鍒嗚唱(zh矛)铏曠悊銆佸垎绱�(j铆)鍒嗚唱(zh矛)鍥炵敤锛屽虎姘村洖鐢ㄧ巼閬�(d谩)鍒扮附铏曠悊姘撮噺鐨�75%浠ヤ笂銆�

閫欎簺鐮旂┒閮借〃鏄庝簡鏈締寤㈡按娣卞害铏曠悊鎶€琛�(sh霉)鐨勭櫦(f膩)灞曟柟鍚�锛屽嵆鍏呭垎鍒╃敤澶氱ó宸ヨ棟鎶€琛�(sh霉)闆嗘垚锛屾彁楂樺虎姘磋檿鐞嗙▼搴︼紝閬�(d谩)鍒板虎姘村惊鐠�(hu谩n)鍥炵敤鏄渶绲傜洰妯�(bi膩o)銆�

3 绲�(ji茅)瑾炲拰灞曟湜

鍗版煋寤㈡按宸茬稉(j墨ng)灏�(du矛)鎴戝湅姘寸挵(hu谩n)澧冩(g貌u)鎴愬毚(y谩n)閲嶅▉鑴咃紝闅ㄨ憲浜哄€戠挵(hu谩n)淇濇剰璀�(sh铆)鐨勫寮�(qi谩ng)锛屽嵃鏌撳虎姘存繁搴﹁檿鐞嗗拰鍥炵敤瓒婁締瓒婂彈鍒版斂搴滅殑闂�(gu膩n)娉�銆傞嚌灏�(du矛)鍗版煋寤㈡按娣卞害铏曠悊鐨勫柈涓€鎶€琛�(sh霉)杓冨涓斿悇鍏峰劒(y艒u)缂洪粸(di菐n)锛屼絾鍧囬洠浠ラ仈(d谩)鍒版帓鏀惧強鍥炵敤妯�(bi膩o)婧�(zh菙n)锛岃鏍规摎(j霉)鍗版煋寤㈡按姘磋唱(zh矛)鐨勭壒榛�(di菐n)锛屽悎鐞嗛伕鎿囧拰鍎�(y艒u)鍖栫祫鍚堣檿鐞嗗伐钘�銆傝啘鍒嗛洟鎶€琛�(sh霉)鏄嵃鏌撳虎姘存繁搴﹁檿鐞嗙殑涓€鍊�(g猫)閲嶈鐮旂┒鏂瑰悜銆傛湭渚嗙爺绌跺彲浠ュ湪鍠厓鎶€琛�(sh霉)鏀归€�(j矛n)鐨勫熀绀�(ch菙)涓�锛屽寘鎷敓鍖�銆佺墿鍖栬檿鐞嗘晥鏋滅殑鎻愰珮銆侀洠闄嶈В鏈夋(j墨)鐗╄檿鐞嗘妧琛�(sh霉)鐨勬敼閫�(j矛n)鍜岃啘绲勪欢姹℃煋鐨勬帶鍒剁瓑锛岃€屽悗褰㈡垚涓€濂楀嚭姘存豢瓒冲洖鐢ㄦ按姘磋唱(zh矛)妯�(bi膩o)婧�(zh菙n)銆佸洖鐢ㄧ巼楂樹笖閬�(y霉n)琛岄珮鏁堢稉(j墨ng)婵�(j矛)鐨勫嵃鏌撳虎姘村洖鐢ㄩ泦鎴愭妧琛�(sh霉)銆�(渚嗘簮锛氬嵃鏌�)