[鎽樿]鑶滃垎闆㈡妧琛�(sh霉)鍦ㄥ嵃鏌撳虎姘磋檿鐞�闋�(l菒ng)鍩熸噳(y墨ng)鐢ㄥ唬娉�锛屽(sh铆)闅涙噳(y墨ng)鐢ㄤ腑锛岃啘姹℃煋闆ｄ互閬垮厤銆傛湰鏂囦粙绱逛簡鑶滃垎闆㈠強闆嗘垚鎶€琛�(sh霉)鍦ㄥ嵃鏌撴按铏曠悊涓殑鎳�(y墨ng)鐢�锛屽垎鏋愪簡鑶滄薄鏌撳瓨鍦ㄧ殑鍘熷洜鍙婅В姹鸿啘姹℃煋鍟忛鐨勭爺绌剁従(xi脿n)鐙€锛岀稖杩颁簡澶氱礆(j铆)閬庢烤銆佸寲瀛�(xu茅)绲嚌銆侀浕绲嚌绛夊墠铏曠悊鎶€琛�(sh霉)锛岄爯(y霉)铏曠悊鍙欢绶╄啘姹℃煋锛屽欢闀疯啘澹藉懡锛岄檷浣庨亱(y霉n)琛屾垚鏈�锛屾槸鑶滃垎闆㈡妧琛�(sh霉)鍦ㄥ嵃鏌撳虎姘存噳(y墨ng)鐢ㄧ殑闂�(gu膩n)閸电挵(hu谩n)绡€(ji茅)锛屽苟灏�(du矛)鑶滃墠闋�(y霉)铏曠悊鎶€琛�(sh霉)鎳�(y墨ng)鐢ㄥ墠鏅€�(j矛n)琛屼簡灞曟湜銆�

闅ㄨ憲宸ユキ(y猫)鏌撴枡鍔犲伐鎶€琛�(sh霉)寰€寰�(f霉)闆滄€�銆佸妯ｆ€х櫦(f膩)灞�锛屽偝绲�(t菕ng)鐨勮檿鐞嗘柟寮忓凡涓嶈兘鏈夋晥铏曠悊鍗版煋寤㈡按锛岃啘鎶€琛�(sh霉)鐮旂┒瓒婁締瓒婂彈鍒颁汉鍊戠殑闂�(gu膩n)娉╗1-5]銆傚湪瀵�(sh铆)闅涙噳(y墨ng)鐢ㄤ腑锛岃啘鐨勬垚鏈磩鍗犳暣鍊�(g猫)绯荤当(t菕ng)鐨勪笁鍒嗕箣涓€锛屽虎姘寸殑姘磋唱(zh矛)鏈�(hu矛)鐩存帴褰遍熆鑶滅殑浣跨敤澹藉懡锛屽洜姝ゅ皪(du矛)寤㈡按閫�(j矛n)琛岄爯(y霉)铏曠悊闈炲父閲嶈[6-7]銆傛湰鏂囬棥杩颁簡鑶滃垎闆㈡妧琛�(sh霉)鍦ㄥ嵃鏌撳虎姘磋檿鐞嗛牁(l菒ng)鍩熺殑鎳�(y墨ng)鐢�锛屾帰瑷庝簡闋�(y霉)铏曠悊鍦ㄥ嵃鏌撳虎姘磋檿鐞嗕腑鐨勫繀瑕佹€�銆�

1 鎳�(y墨ng)鐢ㄤ簬鍗版煋寤㈡按鐨勮啘鍒嗛洟鎶€琛�(sh霉)

鑶滃垎闆㈡妧琛�(sh霉)鏄寚鍊熷姪鑶滅殑閬告搰婊查€忎綔鐢�锛屽湪澶栫晫鑳介噺鎴栧寲瀛�(xu茅)浣嶅樊鐨勪綔鐢ㄤ笅锛屽皪(du矛)鏂欐恫涓殑婧惰唱(zh矛)銆佹憾鍔戦€�(j矛n)琛屽垎闆€€佸垎绱�(j铆)銆佺磾鍖栧拰瀵岄泦鐨勬柟娉昜8]銆傝垏鍌崇当(t菕ng)鐨勭墿鍖�銆佺敓鍖栫瓑铏曠悊宸ヨ棟鐩告瘮锛岃啘鍒嗛洟鎶€琛�(sh霉)娌掓湁鐩歌畩锛屼笉鏈�(hu矛)鏀硅畩鏂欐恫鐨勬€ц唱(zh矛)锛屼笖鎿嶄綔绨″柈锛屽崰鍦伴潰绌嶅皬锛岄亱(y霉n)琛岀┅(w臎n)瀹�銆傚嵃鏌撳虎姘磋檿鐞嗕腑鎳�(y墨ng)鐢ㄨ純澶氱殑鑶滀富瑕佸寘鎷井婵捐啘銆佽秴婵捐啘銆佺磵婵捐啘銆佸弽婊查€忚啘鍜屾柊鍨嬭啘銆�

1.1 寰烤鑶滆垏瓒呮烤鑶�

寰烤鑶滅殑鑶滃瓟寰戝湪0.1~10 渭m 涔嬮枔锛屽伐浣滄(j墨)鐞嗛浼间簬鍌崇当(t菕ng)鐨勯亷婵剧锛屽彲浠ュ幓闄ょ窗(x矛)鑿�銆佸井绮掑拰鑶犲湗(tu谩n)绛変笉婧剁墿銆傝秴婵捐啘鐨勮啘瀛斿緫鍦�0.001~0.02 渭m 涔嬮枔锛屾搷浣滃鍔涘湪0.2~1.0 MPa 涔嬮枔锛屽彲鎴暀鍒嗗瓙閲忕偤1~30 鍗冮亾鐖鹃爴锛坘Da锛夌殑鐗╄唱(zh矛)銆�

寰烤鑶滃唬娉涚敤浜庡嵃鏌撳虎姘磋檿鐞嗛牁(l菒ng)鍩�锛屽皪(du矛)鑹插害鍜孋OD 鍘婚櫎鐜囪純楂樸€傛澶ф槬绛塠9]鐨勭爺绌剁祼(ji茅)鏋滆〃鏄庯細寰烤鑶滃皪(du矛)鎬ц壏绱匵-3B 鏌撴枡妯℃摤寤㈡按鐨勮壊搴︺€丆OD 鐨勫幓闄ょ巼鍒嗗垾閬�(d谩)鍒�99.5 %銆�69.8 %銆侸edidi 绛塠10]閲囩敤寰烤鑶滆檿鐞嗗嵃鏌撳虎姘�锛屽虎姘寸殑鑹插害鍜孋OD 鍘婚櫎鐜囧垎鍒ョ偤90 % 鍜�75 %锛屽嚭姘存縼搴﹀皬浜�0.5 NTU銆傞櫝瓒呭畤绛塠11]閲囩敤寰烤鑶滆檿鐞嗗嵃鏌撳粻浜岀礆(j铆)鐢熷寲鍑烘按锛屾縼搴�100 %鍘婚櫎锛屽嚭姘碨DI 闄嶄綆鑷�2銆�

寰烤鑶滆垏鍏朵粬鎶€琛�(sh霉)绲勫悎灏�(du矛)鍗版煋寤㈡按涔熸湁寰堝ソ鐨勮檿鐞嗘晥鏋�銆傚祰槌寸瓑[12]閲囩敤姘哀鍖栭巶鍚搁檮闋�(y霉)铏曠悊锛岄櫠鐡疯啘寰烤铏曠悊娲绘€ф煋鏂欏虎姘磋劔鑹茶檿鐞�锛岀祼(ji茅)鏋滆〃鏄庡虎姘磋劔鑹茬巼鍙仈(d谩)98 %浠ヤ笂锛岄噰鐢�0.5 mol/L绋€纭濋吀鍖栧(xu茅)娓呮礂锛屽湪涓€瀹氭浠朵笅鍙娇鑶滈€氶噺鏈夋晥鎭㈠京(f霉)銆傚緪绔熸垚绛塠13]閲囩敤寰烤-鍙嶆徊閫忚檿鐞嗗嵃鏌撳虎姘�锛岀櫦(f膩)鐝�(xi脿n)闆栫劧寰烤灏�(du矛)COD 鍜屾縼搴﹀幓闄よ并鐛�(xi脿n)鏈夐檺锛屼絾鏄彲浠ラ€�(j矛n)涓€姝ュ幓闄ゅ虎姘翠腑绱�(x矛)灏忕殑鎳告诞鐗╄唱(zh矛)鍜岃啝楂�锛屼笖寰烤鍑烘按鐨凷DI 姣斿井绲嚌瑕佷綆锛屽彲浠ョ偤鍚庣簩(x霉)鐨勬繁搴﹁檿鐞嗘彁渚涗繚闅�銆�

寮靛媷绛塠14]閲囩敤瓒呮烤-鑶滄帴瑙歌嚟姘ф哀鍖栫祫鍚堝伐钘濊檿鐞嗗嵃鏌撳虎姘�锛岀祼(ji茅)鏋滆〃鏄庤秴婵捐啘鍙娇寤㈡按鐨凜OD 鐢�120~140 mg/L 闄嶄綆鍒�87.7~120.4 mg/L锛屾縼搴︾敱7~21.5 NTU 闄嶄綆鍒�0.55~4.4 NTU銆俍ouD 绛塠15]閲囩敤鏀规€ц秴婵捐啘鍥炵敤鍗版煋寤㈡按锛屾煋鏂欏拰楣界殑鎴暀鐜囬仈(d谩)鍒�98 %锛屼笖pH 鍦�1~14 鑼冨湇鍏�(n猫i)锛岀郴绲�(t菕ng)鍧囬亱(y霉n)琛岃壇濂姐€傚叾浠栧(xu茅)鑰呯殑鐮旂┒涔熻瓑瀵�(sh铆)浜嗚秴婵捐啘鍦ㄥ幓闄よ壊搴�銆佹縼搴�銆佹煋鏂欐柟闈㈡晥鏋滆壇濂絒16-17]銆�

1.2 绱嶆烤鑶滆垏鍙嶆徊閫忚啘

绱嶆烤鑶滆垏鍙嶆徊閫忚啘灞簬澹撳姏椹�(q奴)鍕�(d貌ng)鍨嬭啘锛岀磵婵捐啘鐨勮啘瀛斿緫涓€鑸偤1~2 nm锛屽弽婊查€忚啘鐨勮啘瀛斿緫灏忎簬1 nm銆傜磵婵捐啘鐨勬埅鐣欏垎瀛愰噺鍦�0.2~1 kDa 涔嬮枔锛屼笖澶у鏁�(sh霉)鐐鸿嵎闆昏啘锛屽皪(du矛)鏈夋(j墨)鐗╁拰楂樺児(ji脿)闆㈠瓙鍏锋湁寰堥珮鐨勬埅鐣欑巼锛屽弽婊查€忚啘鍓囦富瑕佸埄鐢ㄨ啘鐨勯伕鎿囬€忛亷鎬у垎闆㈢墿鏂�锛屼竴鑸締瑾�锛屽彧鍏佽ū婧跺姂閫忛亷[18-19]銆�

Bes-Pia 绛塠20]鐨勭爺绌惰〃鏄庯細鍗版煋寤㈡按缍�(j墨ng)鍖栧(xu茅)绲嚌-绱嶆烤鑶滅郴绲�(t菕ng)铏曠悊鍚庯紝绯荤当(t菕ng)鍑烘按鐨凜OD 闄嶄綆鍒�100 mg/L锛岄浕灏�(d菐o)鐜囬檷浣庡埌1000渭s/cm锛岃兘婊胯冻浼佹キ(y猫)鍥炵敤妯�(bi膩o)婧�(zh菙n)銆傞悩楹楃绛塠21]閲囩敤绱嶆烤鑶滃洖鏀跺惈楣芥煋鏂欏虎姘达紝绲�(ji茅)鏋滆〃鏄庤啘灏�(du矛)鍗版煋寤㈡按涓煋鏂欑殑鎴暀鐜囧ぇ浜�99 %锛屾澶栵紝鏌撴枡鐨勬績搴�銆佸搧绋拰楣界殑婵冨害灏�(du矛)鑶滅殑鎴暀鐜囧奖闊胯純灏忥紝宸ヨ棟鍏锋湁杓冨ソ鐨勭稉(j墨ng)婵�(j矛)鎬у拰鍙鎬�銆�

甯稿悜鐪焄22]閲囩敤鐢熷寲鐗╁寲闋�(y霉)铏曠悊-鍙嶆徊閫忚啘灏�(du矛)鍗版煋寤㈡按閫�(j矛n)琛岃檿鐞�锛岀祼(ji茅)鏋滆〃鏄庡嚭姘村悇闋�(xi脿ng)鎸囨(bi膩o)婊胯冻鐢熺敘(ch菐n)鐢ㄦ按瑕佹眰锛屾績姘翠篃鑳介仈(d谩)鍒版帓鏀捐姹�锛屼笖鍏锋湁涓€瀹氱殑缍�(j墨ng)婵�(j矛)鏁堢泭銆傛湵鍏嗕寒绛塠23]閲囩敤闋�(y霉)姘у寲-MBR闋�(y霉)铏曠悊锛屽弽婊查€忚啘鍚庣簩(x霉)铏曠悊鐨勬柟寮忚檿鐞嗗嵃鏌撳虎姘�锛岀祼(ji茅)鏋滆〃鏄庤┎绯荤当(t菕ng)鍑烘按COD 涓嶈秴閬�5 mg/L锛岄浕灏�(d菐o)鐜囦笉瓒呴亷20 渭s/cm锛屽皪(du矛)鏈夎壊鐗╄唱(zh矛)鐨勫幓闄ょ巼閬�(d谩)鍒�90 %~100 %锛岃劔楣界巼鐐�99.5 %~99.7 %銆�

1.3 鏂板瀷鑶�

闄剁摲鑶滄槸涓€绋浉灏�(du矛)杓冩柊鐨勫垎闆㈢敤鐒℃(j墨)鑶滐紝鑶滃瓟寰戜粙浜庡井婵捐啘鍜岃秴婵捐啘涔嬮枔锛屼富瑕佺敱纰冲寲纭呫€佹哀鍖栭媮銆佹哀鍖栭嫰銆佹哀鍖栫銆佹哀鍖栭媴銆佺閰搁媮绛夊埗鎴愶紝鍏锋湁鑰愰珮婧珮澹�銆佽€愯厫铦曘€佷笉鏄撳牭濉�銆佸児(ji脿)鏍间綆寤夌瓑鍎�(y艒u)榛�(di菐n)[24]銆�

Voigt 绛塠25]鍒╃敤TiO2 闄剁摲鑶滆檿鐞嗕簡30 绋笉鍚岀殑鍗版煋寤㈡按锛岀祼(ji茅)鏋滆〃鏄庨櫠鐡疯啘灏�(du矛)寤㈡按鑹插害鐨勫幓闄ょ巼鍧囧湪70 %浠ヤ笂锛屾渶楂樺彲閬�(d谩)100 %锛屽皪(du矛)COD 鐨勫幓闄ょ巼閬�(d谩)45 %~80 %銆傛潕鐓掔瓑[26]閲囩敤伪-Al2O3澶氬瓟闄剁摲鑶滃皪(du矛)鍗版煋寤㈡按閫�(j矛n)琛岃檿鐞�锛屽湪涓€瀹氭浠朵笅锛孋OD 鍜孨H3-N鐨勫幓闄ょ巼鍒嗗垾閬�(d谩)鍒�30 %鍜�20 %宸﹀彸锛屽湪寤㈡按涓坊鍔犱竴瀹氶噺鐨勯珮宥哄湡锛岃啘閫氶噺鏈�(hu矛)鏇撮珮锛孋OD 鐨勫幓闄ょ巼鍙互鎻愰珮鍒�50 %宸﹀彸锛屽叿鏈夎壇濂界殑鐧�(f膩)灞曞墠鏅�銆傛潕鏂版湜绛塠27]閲囩敤闄剁摲鑶滆檿鐞嗗嵃鏌撳虎姘�锛岀暥(d膩ng)閫�(j矛n)姘碈OD锛�200 mg/L锛屾縼搴︼紲5 NTU 鏅�(sh铆)锛屽嚭姘存縼搴﹀皬浜�0.2 NTU锛孲DI 灏忎簬3锛岃啘鐨勯亱(y霉n)琛岄€氶噺鍙互閬�(d谩)鍒�150 L/锛坢2h锛�锛屾竻娲楀懆鏈熷ぇ浜�48 h锛涢€�(j矛n)姘碈OD 婵冨害杓冧綆鏅�(sh铆)锛岄亱(y霉n)琛岄€氶噺鏇撮珮锛屽寲瀛�(xu茅)娓呮礂鏁堟灉鏇翠匠锛屾竻娲楀懆鏈熸洿闀�銆�

鐐啘鏄竴绋柊鍨嬬殑鐒℃(j墨)鍒嗛洟鑶�锛屼富瑕佺敱鐐礌鏉愭枡妲�(g貌u)鎴愶紝鍏锋湁鑰愰吀鍫�銆佽€愭湁姗�(j墨)婧跺姂鑵愯潟鐨勫劒(y艒u)榛�(di菐n)銆傛潕鏂囩繝绛塠28]浠ヨ嚜鍒剁殑妞嶇墿鍩虹偔鑶滆檿鐞嗗嵃鏌撳虎姘�锛岀祼(ji茅)鏋滆〃鏄庤┎鑶滃彲鎴暀寤㈡按涓�99 %鐨勬煋鏂欏垎瀛愩€傞瓘寰瓑[29]閲囩敤鑷埗鐨勭偔鑶滆檿鐞嗘ā鎿嵃鏌撳虎姘�锛屾渶浣虫浠朵笅锛屾煋鏂欑殑鎴暀鐜囧彲閬�(d谩)鍒�100 %銆�

2 鑶滄薄鏌撳強鍏舵垚鍥�

鑶滄薄鏌撴槸鎸囨枡娑蹭腑鐨勫彲婧舵€х殑鐗╄唱(zh矛)鎴栨嚫娴墿娌夌⿳鍦ㄨ啘鐨勮〃闈�銆佸瓟闅欏拰瀛旈殭鍏�(n猫i)澹�锛屽皫(d菐o)鑷磋啘閫氶噺闄嶄綆鐨勭従(xi脿n)璞8锛�18锛�30-32]銆傝啘姹℃煋鍙互鍒嗙偤鍙€嗘薄鏌撳拰涓嶅彲閫嗘薄鏌擄紝鍙€嗘薄鏌撴槸鎸囪啘鐨勮〃闈㈠舰鎴愬嚌鑶犳烤椁呭堡鎴栬€呯櫦(f膩)鐢熸績宸サ鍖�锛屽彲浠ラ€氶亷閬�(y霉n)琛屽懆鏈熻ō(sh猫)瀹氱殑鐗╃悊娓呮礂娑堥櫎锛涚暥(d膩ng)鑶滃瓟琚牭濉炲墖琛ㄦ槑鐧�(f膩)鐢熶簡涓嶅彲閫嗘薄鏌擄紝鐧�(f膩)鐢熶笉鍙€嗘薄鏌撳悗锛岄渶瑕佸皪(du矛)鑶滈€�(j矛n)琛屽寲瀛�(xu茅)娓呮礂鎴栬€呮洿鎻沎18锛�30]銆傚湪瀵�(sh铆)闅涙噳(y墨ng)鐢ㄤ腑锛岃啘姹℃煋鐒℃硶閬垮厤锛屼絾鏈夋晥鐨勯爯(y霉)铏曠悊鑳芥湁鏁堟笡杓曡啘姹℃煋[33]銆�

3 鑶滃墠闋�(y霉)铏曠悊鎶€琛�(sh霉)鍦ㄥ嵃鏌撳虎姘磋檿鐞嗕腑鐨勬噳(y墨ng)鐢�

闋�(y霉)铏曠悊鍙互鍘婚櫎寤㈡按涓殑鎳告诞鐗╀互鍙婅啝楂�锛屾槸淇濊(h霉)鑶滅郴绲�(t菕ng)姝ｅ父閬�(y霉n)琛岀殑閲嶈鏂规硶[34-35]銆傛噳(y墨ng)鐢ㄨ純澶氱殑闋�(y霉)铏曠悊涓昏鏈夎啘闆嗘垚绯荤当(t菕ng)銆佸寲瀛�(xu茅)绲嚌鍜岄浕鍖栧(xu茅)娉曠瓑銆�

3.1 鑶滈泦鎴愮郴绲�(t菕ng)

鑶滈泦鎴愮郴绲�(t菕ng)鏄寚澶氫粙璩�(zh矛)閬庢烤銆佷繚瀹夐亷婵俱€佽啘绛夌祫鍚堜娇鐢ㄧ殑绯荤当(t菕ng)锛岃啘闆嗘垚绯荤当(t菕ng)鑳介仈(d谩)鍒版笡杓曟薄鏌撶殑瑕佹眰锛屼篃鑳藉(sh铆)鐝�(xi脿n)涓嶅悓鐨勫垎闆㈠姛鑳絒8]銆�

榛冪兢璩㈢瓑[36]閲囩敤閶兼福浣滅偤濉枡鍒舵垚鐨勯嫾娓ｉ亷婵惧弽鎳�(y墨ng)鍣ㄥ皪(du矛)鍗版煋寤㈡按閫�(j矛n)琛岃檿鐞�锛岄嫾娓ｉ亷婵惧櫒灏�(du矛)COD銆佹縼搴�銆丼S 鐨勫幓闄ょ巼鍒嗗垾閬�(d谩)鍒�56 %銆�58.3 %銆�50.3 %銆係choeberl 绛塠37]閲囩敤绱嶆烤鑶滆檿鐞嗚啘鐢熺墿鍙嶆噳(y墨ng)鍣ㄧ殑浜岀礆(j铆)鍑烘按锛岀祼(ji茅)鏋滆〃鏄�锛岄爯(y霉)铏曠悊鍙幓闄�80 %鐨凜OD锛岀磵婵捐啘鍑烘按COD 鐐�23.3 mg/L锛屽叾浠栨寚妯�(bi膩o)涔熺鍚堝洖鐢ㄨ姹�銆�

鏇炬澀鎴愮瓑[38]閲囩敤瓒呮烤-鍙嶆徊閫忕祫鍚堝伐钘濊檿鐞嗗嵃鏌撳虎姘�锛岃秴婵鹃爯(y霉)铏曠悊鑳藉幓闄ゅ虎姘翠腑90%鐨勬縼搴�锛屽悓鏅�(sh铆)涔熻兘鍘婚櫎閮ㄥ垎COD锛屼笉鍍呰兘娓涜紩浜嗗弽婊查€忚啘鐨勬薄鏌�锛岃€屼笖鍦ㄤ竴瀹氱▼搴︿笂鎻愰珮浜嗙郴绲�(t菕ng)鐢�(ch菐n)姘存按璩�(zh矛)銆傛潕瀵岀ゥ绛塠39]閲囩敤寰诞鍑�-瓒呮烤-鍙嶆徊閫忚啘鑱�(li谩n)鍚堝伐钘濊檿鐞嗗嵃鏌撳虎姘�锛岀祼(ji茅)鏋滆〃鏄庨爯(y霉)铏曠悊灏�(du矛)寤㈡按婵佸害鐨勫幓闄ょ巼楂橀仈(d谩)98.5 %锛屽皪(du矛)COD銆佽壊搴﹀拰绺�?c猫)鑺欏い鑵唚鐨勫幓闄や篃璧峰埌涓€瀹氱殑浣滅敤锛涢爯(y霉)铏曠悊浣垮弽婊查€忚啘鐨勫寲瀛�(xu茅)娓呮礂鍛ㄦ湡鐢�25 澶╁欢闀峰埌40 澶�锛屽叿鏈夎純濂界殑鎳�(y墨ng)鐢ㄥ墠鏅€傛潕绱呰摦绛塠40]閲囩敤闋�(y霉)铏曠悊-闆欒啘绯荤当(t菕ng)铏曠悊铏曠悊鍗版煋寤㈡按锛岄爯(y霉)铏曠悊閮ㄥ垎閲囩敤澶氫粙璩�(zh矛)閬庢烤鍣ㄥ強婵捐寮忎繚瀹夐亷婵惧櫒锛屽幓闄ゅ浐楂旀薄鏌撶墿銆佹补椤炲拰閮ㄥ垎鑶犻珨绛夌墿璩�(zh矛)锛岄亷婵惧悗鐨勬按閫�(j矛n)鍏ヨ啘绯荤当(t菕ng)锛岃檿鐞嗗悗鐢�(ch菐n)姘存按璩�(zh矛)婵佸害鈮�2mg/L锛孋OD鈮�2 mg/L锛屽嚭姘村彲鍥炵敤浜庣箶甯冪敓鐢�(ch菐n)鐢ㄦ按銆傝瓪鐜夌徍绛塠32]閲囩敤鑷哀姘у寲-鐮傛烤-瓒呮烤-鍙嶆徊閫忛泦鎴愬伐钘濊檿鐞嗗嵃鏌撳虎姘寸敓鍖栬檿鐞嗗嚭姘�锛屽弽婊查€忚啘鑴菇鐜囩┅(w臎n)瀹氬湪98 %锛岀敘(ch菐n)姘撮珮閷抽吀閴€鎸囨暩(sh霉)绱勭偤0.7mg/L锛屾縼搴︾磩鐐�0.12 NTU銆�

鑶滈泦鎴愮郴绲�(t菕ng)涓嶉渶瑕佷娇鐢ㄥ寲瀛�(xu茅)钘ュ姂锛岃兘閬垮厤浜屾姹℃煋銆傜劧鑰屽湪瀵�(sh铆)闅涙噳(y墨ng)鐢ㄤ腑锛屼笉鍚岄鍨嬬殑闋�(y霉)铏曠悊鏂瑰紡閬�(y霉n)琛屾浠朵笉鍚岋紝鑶滅殑姘村洖鏀剁巼绛変篃鏈夋墍涓嶅悓锛屼娇鐢ㄦ渻(hu矛)鍙楀埌涓€瀹氱▼搴︾殑闄愬埗[41]銆�

3.2 鍖栧(xu茅)绲嚌

鍖栧(xu茅)绲嚌鏄寚姘翠腑鎳告诞鐗╂垨鑶犻珨绛夌墿璩�(zh矛)鍦ㄧ诞鍑濆姂鐨勪綔鐢ㄤ笅鍑濊仛鐢熸垚绲湗(tu谩n)娌夐檷鐨勯亷绋媅42锛�43]銆�

Beluci N C L 绛塠44]閲囩敤瓒呮烤鑶滃嵃鏌撳虎姘�锛屽虎姘寸稉(j墨ng)绲嚌闋�(y霉)铏曠悊鍚�锛孯B5 鏌撴枡鍜岃壊搴︾殑鍘婚櫎鐜囬仈(d谩)鍒�100 %锛屼笖鑶滈€氶噺鍥炲京(f霉)鐜囪秴閬�72 %銆傜帇鍊╃瓑[45]閲囩敤鑷埗鐨勫京(f霉)鍚堢诞鍑濆姂PAFC-PDA 铏曠悊妯℃摤娲绘€ц壏钘�(l谩n)KN-R 鍗版煋寤㈡按锛屽湪鏈€浣虫浠朵笅锛屾椿鎬ц壏钘�(l谩n)KN-R 鏌撴枡鍘婚櫎鐜囬仈(d谩)鍒�91 %銆俆ang L 绛塠46]閲囩敤寰�(f霉)鍚堢诞鍑濆姂绲嚌闋�(y霉)铏曠悊鑸囪秴婵捐啘绲勫悎铏曠悊鍗版煋寤㈡按锛屾椿鎬ч粌鑹叉煋鏂欑殑鍘婚櫎鐜囧彲閬�(d谩)86 %锛屼笖缍�(j墨ng)绲嚌闋�(y霉)铏曠悊鍚庯紝鑶滈潰鍘氬害鏈�(hu矛)椤憲澧炲姞锛岃鏄庣稉(j墨ng)绲嚌闋�(y霉)铏曠悊鍚庤啘灏�(du矛)鏌撴枡鍒嗗瓙鐨勬埅鐣欎綔鐢ㄥ寮�(qi谩ng)銆傞櫝鍟熸枌绛塠5]閲囩敤寰敓鐗╃诞鍑濆姂铏曠悊鍗版煋寤㈡按锛屽湪MBF/CaCl2 鐨勮唱(zh矛)閲忔瘮鐐�1锔�32銆丮BF 鐢ㄩ噺鐐�30 mg/L锛宲H 鐐�7.5锛岀诞鍑濇檪(sh铆)闁�20 min 鐨勬儏娉佷笅锛屽彲浠ラ’钁楁彁楂樺悗绾�(x霉)瓒呮烤鑶滅殑鑶滈€氶噺锛岀祫鍚堝伐钘濆皪(du矛)COD 鍘婚櫎鐜囧彲閬�(d谩)鍒�96.07 %锛屾按鍥炵敤鐜囧彲閬�(d谩)83 %锛岃€屼笖灏�(du矛)瓒呮烤鑶滅殑澹藉懡褰遍熆杓冨皬銆�

鍖栧(xu茅)绲嚌鍙楁按璩�(zh矛)銆佹韩搴︾瓑姊濅欢褰遍熆杓冨ぇ锛屽皪(du矛)绲嚌鍔戠殑绋鍜岀敤閲忚姹備篃杓冮珮锛屾枡娑蹭腑涔熷彲鑳芥渻(hu矛)娈樼暀閻�銆侀媮绛夐洟瀛�锛屼娇鐢ㄤ笉鐣�(d膩ng)鍙兘鏈�(hu矛)閫犳垚涓嶅彲閫嗘薄鏌揫42锛�47]銆傛澶�锛屽寲瀛�(xu茅)绲嚌鐢�(ch菐n)鐢熺殑姹℃偿涔熼渶瑕佸彟澶栬檿缃甗5]銆�

3.3 闆诲偓鍖栨妧琛�(sh霉)

闆诲偓鍖栨哀鍖栨妧琛�(sh霉)鏄寚姘撮珨涓殑鏈夋(j墨)鐗╄闆绘サ鍜屽偓鍖栨潗鏂欑敘(ch菐n)鐢熺殑寮�(qi谩ng)姘у寲鎬у熀鍦�(tu谩n)姘у寲鐨勯亷绋�锛岄浕鍌寲姘у寲鍙互鏇村竟搴曞湴鍒嗚В鏈夋(j墨)鐗╋紝涓斾笉鏄撶敘(ch菐n)鐢熸湁姣掔墿璩�(zh矛)[48]銆�

寮垫捣姘戠瓑[49]閲囩敤鑷埗鐨凾iO2/Al2O3 寰�(f霉)鍚堝垎闆㈣啘铏曠悊鍗版煋寤㈡按锛屽湪鍏夊偓鍖栨浠朵笅锛岀郴绲�(t菕ng)灏�(du矛)Black 168 鐨勫幓闄ょ巼鑳介仈(d谩)鍒�80 %銆傞珮姘哥瓑[50]閲囩敤TiO2 鍏夊偓鍖�-寰烤鑶滅祫鍚堝伐钘濊檿鐞嗗嵃鏌撳虎姘达紝绯荤当(t菕ng)铏曠悊鍑烘按COD銆丅OD銆佽壊搴﹀拰婵佸害鍒嗗垾鐐�35 mg/L銆�2.7 mg/L銆�3鍊�銆�2.3 NTU锛屽彲浣滅偤闈炲伐钘濈敤姘撮€�(j矛n)琛屽洖鐢�銆傛潕寤烘柊绛塠51]閲囩敤闆诲偓鍖栬啘灏�(du矛)浜炵敳鍩鸿棈(l谩n)婧舵恫閫�(j矛n)琛岃檿鐞�锛岃檿鐞嗗悗鑹插害鍘婚櫎鐜囨帴杩�100 %锛屼笖婧舵恫涓殑鍣诲惄鍡鍖栧悎鐗╁畬鍏ㄩ檷瑙�銆�

闆诲偓鍖栧叿鏈夊緢澶氬劒(y艒u)榛�(di菐n)锛岀劧鑰屽湪瀵�(sh铆)闅涙噳(y墨ng)鐢ㄤ腑锛屽嵃鏌撳虎姘存垚鍒嗚純鐐哄京(f霉)闆滐紝瀹规槗閫犳垚鍏夊偓鍖栧姂鐨勪腑姣�锛涘叾娆★紝鍌寲鍔戦洠浠ュ洖鏀�锛屾椿鎬х祫鍒嗘悕澶卞ぇ锛屾渻(hu矛)灏�(du矛)鐠�(hu谩n)澧冮€犳垚浜屾姹℃煋[51]銆傛澶栵紝鍦ㄥ(sh铆)闅涙噳(y墨ng)鐢ㄤ腑闆诲偓鍖栬兘鑰楄純楂�锛岃閫�(j矛n)琛屾帹寤ｉ倓闇€瑕佸姞寮�(qi谩ng)灏�(du矛)闆绘サ鏉愭枡鐨勭爺绌禰52]銆�

3.4 闆荤诞鍑�

闆荤诞鍑濇硶鏄寚浣跨敤閶併€侀惖绛夐噾灞綔鐐洪櫧妤�锛屽湪鐩存祦闆荤殑浣滅敤涓嬬敘(ch菐n)鐢熼媮銆侀惖绛夐洟瀛�锛岃垏闄版サ闆昏В鐢�(ch菐n)鐢熺殑-OH 缍�(j墨ng)姘磋В銆佽仛鍚堢瓑閬庣▼褰㈡垚鍚勭ó缇ュ熀绲�(lu貌)鍚堢墿銆佸鏍哥茎鍩虹怠(lu貌)鍚堢墿锛屼娇寤㈡按涓殑鑶犻珨鍜屾嚫娴墿鍑濊仛娌夋穩鑰屽垎闆㈢殑閬庣▼[53]銆傞浕绲嚌鎶曡硣鎴愭湰浣�锛屽彲鎺ф€у挤(qi谩ng)锛岀敘(ch菐n)鐢熺殑姹℃偿灏戜笖姹℃偿鍚按閲忎綆锛岃€屼笖鐢变簬闄芥サ鐨勬哀鍖栦綔鐢ㄥ拰闄版サ鐨勯倓鍘熶綔鐢�锛屽彲鍘婚櫎澶氱ó姹℃煋鐗54]銆�

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