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7.绲�(lu貌)鍚堟硶
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4銆佺敓鐗╄劔纭細
鐢熺墿鑴～锛屽張绋辩敓鐗╁偓鍖栬劔纭紙绨＄ūBDS锛�锛屾槸涓€绋湪甯告韩甯稿涓嬪埄鐢ㄩ渶姘�銆佸幁姘ц弻闄ゅ幓鐭虫补鍚～闆滅挵(hu谩n)鍖栧悎鐗╀腑绲�(ji茅)鍚堢～鐨勪竴绋柊鎶€琛�(sh霉)銆傛棭鍦�1948骞寸編鍦嬪氨鏈変簡鐢熺墿鑴～鐨勫皥鍒�锛屼絾涓€鐩存矑鏈夋垚鍔熻劔闄ょ兇椤炵～鍖栫墿鐨勫渚�锛屽叾涓昏鍘熷洜鏄笉鑳芥湁鏁堢殑鎺у埗绱�(x矛)鑿岀殑浣滅敤銆傛鍚庢湁骞惧€嬫垚鍔熺殑鈥滃井鐢熺墿鑴～鈥濆牨閬�锛屼絾鍗绘矑鏈夊灏戞噳(y墨ng)鐢ㄥ児鍊�锛屽師鍥犲湪浜庡井鐢熺墿鐩＄鑴幓浜嗘补涓殑纭紝浣嗗悓鏅備篃娑堣€椾簡娌逛腑鐨勮ū澶氱偔鑰屾笡灏戜簡娌逛腑鐨勮ū澶氭斁鐔遍噺?锛熻寲W(xu茅)宸ヤ綔鑰呬竴鐩村皪鍏堕€�(j矛n)琛屼簡娣卞叆鐨勭爺绌�锛岀洿鍒�1998骞寸編鍦嬬殑InstituteofGasTechnology(IGT锛夌殑鐮旂┒浜哄摗鎴愬姛鐨勫垎闆簡鍏╃ó鐗规畩鐨勮弻鏍紝閫欏叐绋弻鏍彲浠ユ湁閬告搰鎬х殑鑴櫎浜岃嫰骞跺櫥鍚╀腑鐨勭～锛屽幓闄ゆ补鍝佷腑闆滅挵(hu谩n)纭垎瀛愮殑宸ユキ(y猫)鍖栨ā鍨嬬浉绻肩敘(ch菐n)鐢燂紝1992骞村湪缇庡湅鍒嗗垾鐢宠珛浜嗗叐闋呭皥鍒╋紙5002888鍜�5104801锛夈€傜編鍦婨nergyBioSystemsCorp(EBC)鍏徃鐛插緱浜嗛€欏叐绋弻鏍殑浣跨敤娆�(qu谩n)锛屽湪姝ゅ熀绀�(ch菙)涓�锛岃┎鍏徃涓嶅儏鎴愬姛鍦扮敓鐢�(ch菐n)鍜屽啀鐢熶簡鐢熺墿鑴～鍌寲鍔戯紝骞跺湪闄嶄綆鍌寲鍔戠敓鐢�(ch菐n)鎴愭湰鐨勫悓鏅備篃寤堕暦浜嗗偓鍖栧姂鐨勪娇鐢ㄥ＝鍛�銆傛澶栬┎鍏徃鍙堝垎闆㈠緱鍒颁簡鐜椿鐞冭弻鐨勭窗(x矛)鑿岋紝瑭茬窗(x矛)鑿岃兘澶犱娇C-S閸垫柗瑁�锛屽鐝�(xi脿n)浜嗚劔纭亷绋嬩腑涓嶆悕澶辨补鍝佺兇椤炵殑鐩殑?锛孎(xi脿n)鍦紝EBC鍏徃宸叉垚鐐轰笘鐣屼笂灏嶇敓鐗╄劔纭妧琛�(sh霉)鐮旂┒鏈€寤ｆ硾鐨勫叕鍙�銆傛澶�锛屾棩鏈伐妤�(y猫)鎶€琛�(sh霉)鐮旂┒闄㈢敓鍛藉伐绋嬪伐妤�(y猫)鎶€琛�(sh霉)鐮旂┒鎵€鑸囩煶娌圭敘(ch菐n)妤�(y猫)娲诲寲涓績鑱�(li谩n)鍚堥枊鐧�(f膩)鍑轰簡鏌存补鑴～鐨勬柊鑿岀ó锛屾鑿岀ó鍙互鍚屾檪鑴櫎鏌存补涓殑浜岃嫰骞跺櫥鍚╁拰鑻苟鍣诲惄涓殑纭紝鑰岄€欏叐绋～鍖栫墿涓殑纭槸鐢ㄥ叾瀹冩柟娉曢洠浠ヨ劔闄ょ殑銆�
BDS閬庣▼鏄互鑷劧鐣岀敘(ch菐n)鐢熺殑鏈夋哀绱�(x矛)鑿岃垏鏈夋(j墨)纭寲鐗╃櫦(f膩)鐢熸哀鍖栧弽鎳�(y墨ng)锛岄伕鎿囨€ф哀鍖栦娇C-S閸垫柗瑁�锛屽皣纭師瀛愭哀鍖栨垚纭吀楣芥垨浜炵～閰搁菇杞�(zhu菐n)鍏ユ按鐩�锛岃€孌BT鐨勯鏋剁祼(ji茅)妲�(g貌u)姘у寲鎴愮茎鍩鸿伅(li谩n)鑻暀鍦ㄦ补鐩�锛屽緸鑰岄仈(d谩)鍒拌劔闄ょ～鍖栫墿鐨勭洰鐨勩€侭DS鎶€琛�(sh霉)寰炲嚭鐝�(xi脿n)鑷充粖宸茬櫦(f膩)灞曚簡骞惧崄骞�锛岀洰鍓嶇偤姝粛铏曚簬闁嬬櫦(f膩)鐮旂┒闅庢銆傜敱浜嶣DS鎶€琛�(sh霉)鏈夎ū澶氬劒(y艒u)榛�锛屽畠鍙互鑸囧凡鏈夌殑HDS瑁濈疆鏈夋(j墨)绲勫悎锛屼笉鍍呭彲浠ュぇ骞呭害鍦伴檷浣庣敓鐢�(ch菐n)鎴愭湰锛岃€屼笖鐢变簬鏈夋(j墨)纭敘(ch菐n)鍝佺殑闄勫姞鍊艰純楂�锛孊DS姣擧DS鍦ㄧ稉(j墨ng)婵�(j矛)涓婃湁鏇村挤(qi谩ng)鐨勭鐖姏銆傚悓鏅侭DS閭勫彲浠ヨ垏鍌寲鍚搁檮鑴～绲勫悎锛屾槸瀵︾従(xi脿n)灏嶇噧鏂欐补娣卞害鑴～鐨勬湁鏁堟柟娉�銆傚洜姝DS鎶€琛�(sh霉)鍏锋湁寤ｉ棅鐨勬噳(y墨ng)鐢ㄥ墠鏅紝闋�(y霉)瑷堝湪2010骞村乏鍙冲皣鏈夊伐妤�(y猫)鍖栬缃嚭鐝�(xi脿n)銆�
5銆佹柊鍨嬭劔纭細
1.姘у寲鑴～鎶€琛�(sh霉)
姘у寲鑴～鎶€琛�(sh霉)鏄敤姘у寲鍔戝皣鍣诲惄椤炵～鍖栫墿姘у寲鎴愪簽鐮滃拰鐮�锛屽啀鐢ㄦ憾鍔戞娊鎻愮殑鏂规硶灏囦簽鐮滃拰鐮滃緸娌瑰搧涓劔闄�锛屾哀鍖栧姂缍�(j墨ng)閬庡啀鐢熷悗寰挵(hu谩n)浣跨敤銆傜洰鍓嶇殑浣庣～鏌存补閮芥槸閫氶亷鍔犳矮鎶€琛�(sh霉)鐢熺敘(ch菐n)鐨�锛岀敱浜庢煷娌逛腑鐨勪簩鐢插熀浜岃嫰骞跺櫥鍚╃祼(ji茅)妲�(g貌u)绌�(w臎n)瀹氫笉鏄撳姞姘劔纭�锛岀偤浜嗕娇娌瑰搧涓殑纭惈閲忛檷鍒�10渭g/g锛岄渶瑕佹洿楂樼殑鍙嶆噳(y墨ng)澹撳姏鍜屾洿浣庣殑绌洪€�锛岄€欑劇鐤戝鍔犱簡鍔犳矮鎶€琛�(sh霉)鐨勬姇璩囪不鐢ㄥ拰鐢熺敘(ch菐n)鎴愭湰銆傝€屾哀鍖栬劔纭妧琛�(sh霉)涓嶅儏鍙互婊胯冻灏嶆煷娌归ぞ鍒�10渭g/g鐨勮姹�锛岄倓鍙互鍐嶅垎閵风恫(w菐ng)榛炶ō(sh猫)缃啊渚垮彲琛岀殑鑴～瑁濈疆锛屾槸婊胯冻鏈€绲傞姺鍞补鍝佽唱(zh矛)閲忕殑杓冨ソ閫斿緫銆�
2.ASR-2姘у寲鑴～鎶€琛�(sh霉)
ASR-2姘у寲鑴～鎶€琛�(sh霉)鏄敱Unipure鍏徃闁嬬櫦(f膩)鐨勪竴绋柊鍨嬭劔纭妧琛�(sh霉)锛屾鎶€琛�(sh霉)鍏锋湁鎶曡硣鍜屾搷浣滆不鐢ㄤ綆銆佹搷浣滄浠剁珐鍜�銆佷笉闇€瑕佹矮婧�銆佽兘鑰椾綆銆佺劇姹℃煋鎺掓斁銆佽兘鐢熺敘(ch菐n)瓒呬綆纭煷娌�銆佽缃缓瑷�(sh猫)闈堟椿绛夊劒(y艒u)榛�锛岀偤鐓夋补寤犲拰鍒嗛姺缍�(w菐ng)榛炴彁渚涗簡涓€鍊嬬稉(j墨ng)婵�(j矛)銆佸彲闈犵殑婊胯冻娌瑰搧纭惈閲忚姹傜殑鏂规硶銆�
鍦ㄥ椹楅亷绋嬩腑锛屾鎶€琛�(sh霉)鑳芥妸鏌存补涓殑纭惈閲忕敱7000渭g/g鏈€绲傞檷鍒�5渭g/g銆傛澶栬┎鎶€琛�(sh霉)閭勫彲浠ョ敤渚嗙敓鐢�(ch菐n)瓒呬綆纭煷娌癸紝渚嗕綔鐐烘补鍝佺殑瑾�(di脿o)鍜岀祫鍒�锛屼互婊胯冻娌瑰搧鍔犲伐鍜岄姺鍞競鍫寸殑闇€瑕�銆傜洰鍓岮SR-2鎶€琛�(sh霉)姝ｅ湪閫�(j矛n)琛屼腑瑭﹀拰宸ユキ(y猫)瀵﹂鐨勮ō(sh猫)瑷堝伐浣�銆傚叾宸ヨ棟娴佺▼濡備笅锛氬惈纭煷娌硅垏姘у寲鍔戝強鍌寲鍔戠殑姘寸浉鍦ㄥ弽鎳�(y墨ng)鍣ㄥ収(n猫i)娣峰悎锛屽湪鎺ヨ繎甯稿鍜岀珐鍜岀殑婧害涓嬪皣鍣诲惄椤炲惈纭寲鍚堢墿姘у寲鎴愮牅锛涚劧鍚庡皣鍚湁寰呯敓鍌寲鍔戝拰鐮滅殑姘寸浉鑸囨补鐩稿垎闆㈠悗閫佽嚦鍐嶇敓閮ㄥ垎锛岄櫎鍘荤牅骞跺啀鐢熷偓鍖栧姂锛涘惈鏈夌牅鐨勬补鐩搁€佽嚦钀冨彇绯荤当(t菕ng)锛屽鐝�(xi脿n)鐮滃拰娌圭浉鍒嗛洟锛涚敱姘寸浉鍜屾补鐩稿緱鍒扮殑鐮滀竴璧烽€佸埌铏曠悊绯荤当(t菕ng)锛屼締鐢熺敘(ch菐n)楂橀檮鍔犲€肩殑鍖栧伐鐢�(ch菐n)鍝併€�
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3.瓒呰伈娉�姘у寲鑴～鎶€琛�(sh霉)
瓒呰伈娉㈡哀鍖栬劔纭�(SulphCo)鎶€琛�(sh霉)鏄敱USC鍜孲ulphCo鍏徃鑱�(li谩n)鍚堥枊鐧�(f膩)鐨勬柊鍨嬭劔纭妧琛�(sh霉)銆傛鎶€琛�(sh霉)鐨勫寲瀛�(xu茅)鍘熺悊鑸嘇SR-2鎶€琛�(sh霉)鍩烘湰鐩稿悓锛屼笉鍚屼箣铏曟槸SulphCo鎶€琛�(sh霉)閲囩敤浜嗚秴鑱叉尝鍙嶆噳(y墨ng)鍣�锛屽挤(qi谩ng)鍖栦簡鍙嶆噳(y墨ng)閬庣▼锛屼娇鑴～鏁堟灉鏇村姞鐞嗘兂銆傚叾娴佺▼鎻忚堪鐐猴細鍘熸枡鑸囧惈鏈夋哀鍖栧姂鍜屽偓鍖栧姂鐨勬按鐩稿湪鍙嶆噳(y墨ng)鍣ㄥ収(n猫i)娣峰悎锛屽湪瓒呰伈娉㈢殑浣滅敤涓嬶紝灏忔埃娉¤繀閫熺殑鐢�(ch菐n)鐢熷拰鐮存粎锛屽緸鑰屼娇娌圭浉鑸囨按鐩稿妵鐑堟贩鍚堬紝鍦ㄧ煭鏅傞枔鍏�(n猫i)瓒呰伈娉㈤倓鍙互浣挎贩鍚堢墿鏂欏収(n猫i)鐨勫眬閮ㄦ韩搴﹀拰澹撳姏杩呴€熷崌楂�锛屼笖鍦ㄦ贩鍚堢墿鏂欏収(n猫i)鐢�(ch菐n)鐢熼亷姘у寲姘�锛屽弮鑸囩～鍖栫墿鐨勫弽鎳�(y墨ng)锛涚稉(j墨ng)婧跺姂钀冨彇鑴櫎鐮滃拰纭吀楣斤紝婧跺姂鍐嶇敓鍚庡惊鐠�(hu谩n)浣跨敤锛岀牅鍜岀～閰搁菇鍙互鐢熺敘(ch菐n)鍏朵粬鍖栧伐鐢�(ch菐n)鍝�銆�
SulphCo鍦ㄥ畬鎴愬椹楀宸ヤ綔鍚�锛屽張閫�(j矛n)琛屼簡涓│鏀惧ぇ瀵﹂锛屽彇寰椾簡浠や汉婊挎剰鐨勬晥鏋�锛屽嵆涓嶅悓纭惈閲忕殑鏌存补缍�(j墨ng)閬庢哀鍖栬劔纭妧琛�(sh霉)鍚庣～鍚噺鍧囪兘闄嶄綆鍒�10渭g/g浠ヤ笅銆傜洰鍓岯echtel鍏徃姝ｅ湪钁楁墜SulphCo鎶€琛�(sh霉)鐨勫伐妤�(y猫)瑭﹂銆�
4.鍏�銆佺瓑闆㈠瓙楂旇劔纭妧琛�(sh霉)
鏃ユ湰姹℃煋鍜岃硣婧愬湅瀹剁爺绌堕櫌銆佸痉鍦婽ubingen澶у(xu茅)绛夊柈浣嶇爺绌剁敤绱鍏夌収灏勫強绛夐洟瀛愰珨鎶€琛�(sh霉)鑴～銆傚叾姗�(j墨)鐞嗘槸锛氫簩纭寲鐗╂槸閫氶亷S-S閸垫柗瑁傚舰鎴愯嚜鐢卞熀锛岀～閱氬拰纭唶鍒嗗垾鏄疌-S鍜孲-H閸垫柗瑁傚舰鎴愯嚜鐢卞熀锛屽苟鎸変笅鍒楁柟寮忛€�(j矛n)琛屽弽鎳�(y墨ng)锛�
鐒℃哀鍖栧姂姊濅欢涓嬬殑鍙嶆噳(y墨ng)锛�
CH3S-+-CH3CH4+CH2====S
CH3S-+CH3CH2RCH3SH+CH2====SCH2R
CH3S-+CH3S-CH3SSCH3
CH3S-+CH2====SCH3SCH2S--CH3CH3SCH2SCH3
鏈夋哀鍖栧姂姊濅欢涓嬬殑鍙嶆噳(y墨ng)锛�
CH3S-+O2CH3SOO-RHCH3SOOH+R-
SO3+-CH3
CH3SOOHRrCH3SO-+-OH
CH3SO-+RHCH3SOH+R-
3CH3SOOHCH3SOOSCH3+CH3SO3H
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5.楂樻晥闇у寲鑴～闄ゅ〉鎶€琛�(sh霉)
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鎶€琛�(sh霉)鍎�(y艒u)鍕細
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