姒傛嫭绺界祼(ji茅)浜嗚繎骞翠締鍦嬪収(n猫i)澶栭櫧闆㈠瓙鍨嬫湁姗�(j墨)楂樺垎瀛愮诞鍑濆姂鍦ㄥ惈娌规薄姘磋檿鐞�涓殑鎳�(y墨ng)鐢ㄦ儏娉�; 閲嶉粸(di菐n)浠嬬垂浜嗗凡鐢ㄤ簬铏曠悊鍚补姹℃按鐨勯櫧闆㈠瓙鍨嬩汉宸ュ悎鎴愰珮鍒嗗瓙绲嚌鍔戠殑姗�(j墨)鐞嗐€佸埗鍌欐柟娉�銆佺ó椤�銆佹€ц兘銆佹噳(y墨ng)鐢ㄦ柟娉曚互鍙婂皪鍚补姹℃按鐨勬噳(y墨ng)鐢ㄦ晥鏋�; 骞跺皪鏀规€ч櫧闆㈠瓙鍨嬪ぉ鐒舵湁姗�(j墨)楂樺垎瀛愮诞鍑濆姂鐨勭櫦(f膩)灞曞墠鏅仛鍑轰簡灞曟湜銆�

[闂�(gu膩n)閸佃] 闄介洟瀛愬瀷鏈夋(j墨)楂樺垎瀛� 绲嚌鍔� 鍚补姹℃按 鎳�(y墨ng)鐢�

绲曞ぇ閮ㄥ垎娌圭敯鐨勯枊閲囧凡缍�(j墨ng)閫�(j矛n)鍏ヤ笁娆￠噰娌归殠娈�銆傜偤浜嗘彁楂橀噰鏀剁巼锛屽寲瀛�(xu茅)椹�(q奴)鎶€琛�(sh霉)寰楀埌寤ｆ硾鎳�(y墨ng)鐢ㄣ€傛补灞や腑閲囧嚭鐨勬薄姘村拰鍦伴潰铏曠悊銆侀墕浜�銆佷綔妤�(y猫)閬庣▼涓帓鍑虹殑姹℃按鍖仛鍦ㄤ竴璧�锛岄€犳垚姹℃按涓﹨(q奴)娌瑰姂銆佹补銆佹嚫娴墿銆佹偿鐮備互鍙婃(j墨)姊伴洔璩�(zh矛)绛夊惈閲忛珮锛屼娇姘磋唱(zh矛)鐨�鍑堝寲寰堥洠铏曠悊[1]銆�

鐩墠娌圭敯姹℃按鐨勫噲鍖栧唬娉涗娇鐢ㄧ殑鏂规硶鏄诞鍑濇矇娣€娉曪紝涔熷氨鏄悜姘翠腑鍔犲叆绲嚌鍔�銆傚柈鐛�(d煤)浣跨敤鐒℃(j墨)绲嚌鍔戯紝瀛樺湪鍔犺棩閲忓ぇ锛屾按涓敓鎴愭矇娣€杓冨锛屾槗鐢�(ch菐n)鐢熷ぇ閲忔薄娉ュ拰娴福锛屼笖灏嶅姞钘ヨō(sh猫)鍌欍€佺绶氱殑闃茶厫鏈夎純楂樿姹傜瓑缂洪粸(di菐n)锛屽凡缍�(j墨ng)寰堥洠婊胯冻姘磋檿鐞嗙殑瑕佹眰銆傞櫧闆㈠瓙鏈夋(j墨)绲嚌鍔戜笉鍍呭厠鏈嶇劇姗�(j墨)绲嚌鍔戠殑閫欎簺缂洪粸(di菐n)锛岃€屼笖鍦ㄥ挤(qi谩ng)鍖栫诞鍑濋櫎鍘婚洠鐢熺墿闄嶈В鏈夋(j墨)姹℃煋鐗╂柟闈㈣〃鐝�(xi脿n)鍑轰簡宸ㄥぇ鐨勫劒(y艒u)鍕㈠拰鎳�(y墨ng)鐢ㄥ墠鏅�銆傝繎浜涘勾渚嗙櫦(f膩)灞曠殑灏囦簩鑰呭京(f霉)閰嶅緱鍒板唬娉涙噳(y墨ng)鐢�锛屽叿鏈夊緢濂界殑鐠�(hu谩n)澧冨拰缍�(j墨ng)婵�(j矛)鏁堢泭銆傚湪涓嶆敼璁婄従(xi脿n)鏈夎檿鐞嗗伐钘濈殑鎯呮硜涓�锛岀爺鍒跺苟鎳�(y墨ng)鐢ㄩ珮鏁堢诞鍑濆姂锛屾噳(y墨ng)瑭叉槸涓夋閲囨补铏曠悊姹℃按杓冪偤缍�(j墨ng)婵�(j矛)鐨勬柟娉�銆備笅闈㈠皣灏嶈繎骞翠締闄介洟瀛愬瀷鏈夋(j墨)楂樺垎瀛愮诞鍑濆姂鍦ㄦ补鐢版薄姘磋檿鐞嗕腑鐨勬噳(y墨ng)鐢ㄤ綔鎵艰鐨勭稖杩般€�

1 闄介洟瀛愬瀷浜哄伐鍚堟垚鏈夋(j墨)楂樺垎瀛愮诞鍑濆姂

闄介洟瀛愬瀷浜哄伐鍚堟垚鏈夋(j墨)楂樺垎瀛愮诞鍑濆姂鏄竴绋珮鍒嗗瓙鑱氶浕瑙ｈ唱(zh矛)锛屽叿鏈夊垎瀛愰噺澶�銆侀張鐨勪几灞曞害澶э紝鍙互璧峰埌闆绘€т腑鍜�銆佸惛闄勬灦姗嬨€佷娇楂旂郴涓殑寰矑鑴┅(w臎n)鑱氱祼(ji茅)绛変綔鐢�銆傜敱浜庡悎鎴愮殑闄介洟瀛愯仛闆昏В璩�(zh矛)鐨勬噳(y墨ng)鐢ㄦ€ц兘寰堝ソ锛屽洜鑰屽緢澶氬(xu茅)鑰呭湪閫欐柟闈㈤枊灞曚簡鍗佸垎寤ｆ硾鐨勭爺绌�銆�

1.1 鑱氫笝鐑叞鑳洪

1.1.1 闄介洟瀛愯仛涓欑儻閰拌兒椤�

闅ㄨ憲娌圭敯闁嬬櫦(f膩)鏅傞枔鐨勫欢闀峰強鍚勭ó鎻愰珮閲囨敹鐜囨妧琛�(sh霉)鐨勫(sh铆)鏂�锛屼笁娆￠噰娌瑰寲瀛�(xu茅)椹�(q奴)鎶€琛�(sh霉)鐨勬帹寤ｄ娇鐢�锛屾补鐢伴噰鍑烘按鐨勬垚浠戒腑涔熷惈鏈夌浉鎳�(y墨ng)鐨勯﹨(q奴)娌瑰姂鎴愬垎锛岄€欏氨浣垮緱閲囧嚭姘寸殑鎬ц唱(zh矛)鏇村姞寰�(f霉)闆溿€傜爺绌剁櫦(f膩)鐝�(xi脿n)鍚补姹℃按涓墍鍚嚫娴墿鍜岃啝楂旈绮掍互鍙婇櫚闆㈠瓙鑱氫笝鐑叞鑳�(HPAM) 姘磋В涔嬪悗甯惰矤(f霉)闆昏嵎锛岄櫧闆㈠瓙鑱氫笝鐑叞鑳�(CPAM) 鍙垏姘翠腑鐨勫井绮掑悓鏅傝捣鍒伴浕涓拰鍙婂惛闄勬灦姗嬩綔鐢�锛屽緸鑰屼娇姹℃按涓殑寰矑鑴┅(w臎n)銆佺诞鍑濊€岄仈(d谩)鍒拌壇濂界殑铏曠悊鏁堟灉[2]銆傚叾涓敼鎬PAM 浠ュ叾鏇撮’钁楃殑鎬ц兘鑰屽崰鏈夎純澶ф瘮渚嬨€侰PAM 鐨勫埗鍌欓€氬父鏄閵ㄥ寲鐨勮仛涓欑儻閰拌兒(AM) 锛屽皣鈥擭H2缍�(j墨ng)閬庣茎鐢插熀鍖栧拰瀛ｉ姩鍖栬€屽緱锛屽彟澶栧氨鏄敱AM 鑸囬櫧闆㈠瓙鍠珨鍏辫仛鍚堝緱鍒�銆傝稒濞滃[3]鐢―AC 鑸嘇M 鍏辫仛鍚堟垚鍑虹殑CPAM 铏曠悊娓ゆ捣娌圭敯鐝�(xi脿n)鍫存薄姘�锛岀敤閲忕偤20 mg /L锛屽幓娌圭巼閬�(d谩)鍒�87锛�8%銆傝稒浠曟灄[4]浣跨敤P(DMC-AM) 铏曠悊鍚勭ó寤㈡按锛孋ODCr鐨勫幓闄ょ巼鍙仈(d谩)65% 锝� 90%銆�

1.1.2 寰�(f霉)閰嶉櫧闆㈠瓙鑱氫笝鐑叞鑳洪

澶ч噺鐨勫(sh铆)韪愯〃鏄�锛岃嫢鎶婂叐绋垨鍏╃ó浠ヤ笂鐨勭诞鍑濆姂閫氶亷鍒嗗垾鎶曞姞鑰岄€�(j矛n)琛屽京(f霉)閰嶄娇鐢ㄣ€佹垨鍦ㄤ竴瀹氭浠朵笅閫氶亷娣峰悎鎴栧弽鎳�(y墨ng)褰㈡垚涓€绋京(f霉)鍚堢诞鍑濆姂鐢�(ch菐n)鍝佷娇鐢�锛岃棩鍔戦枔鍏锋湁鈥滃崝(xi茅)鍚屾晥鎳�(y墨ng)鈥�锛屽彲鎻愰珮钘ュ姂鍠崹(d煤)浣跨敤鐨勬晥鏋�銆侰PAM鐨勮檿鐞嗘晥鏋滃ソ浜庡厓姗�(j墨)绲嚌鍔戯紝浣嗗叾鎴愭湰楂�锛屽柈鐛�(d煤)浣跨敤鐒℃(j墨)绲嚌鍔戝叾鍔犺棩閲忓張澶ぇ銆傝〃1鍒楀嚭浜嗗凡鐭ョ殑骞剧ó閰嶆柟鎴愬垎寰�(f霉)閰嶈棩鍔戣檿鐞嗘补鐢版薄姘存晥鏋溿€�

琛�1 寰�(f霉)閰嶈仛涓欑儻閰拌兒铏曠悊鍚补姹℃按鏁堟灉

寰炶〃1 涓彲鐪嬪嚭锛屽悇绋厤鏂硅檿鐞嗕笉鍚屾€ц唱(zh矛)鐨勫惈娌规薄姘�锛岄櫎娌圭巼銆佹嚫娴墿鍘婚櫎鐜囪兘閬�(d谩)鍒�90% 浠ヤ笂銆傛瘡涓€绋京(f霉)閰嶆晥鏋滆垏鍠崹(d煤)浣跨敤鐒℃(j墨)绲嚌鍔戠殑鐩告瘮[5-8]锛屽京(f霉)鍚堜娇鐢ㄥ彲浠ラ檷浣庤棩鍔戠敤閲�锛岄檷浣庢垚鏈�銆�

1.2鑱氫簩鐢插熀浜岀儻涓欏熀姘寲閵ㄩ

1.2.1鑱氫簩鐢插熀浜岀儻涓欏熀姘寲閵ㄩ

浜岀敳鍩轰簩鐑笝鍩烘隘鍖栭姩鐨勫潎鑱氱墿鍜屽叡鑱氱墿鍏锋湁寰堥珮鐨勯浕鑽峰瘑搴�锛屾サ鏄撴憾浜庢按骞跺叿鏈夊劒(y艒u)鑹殑鐮翠钩绲嚌鎬ц兘锛岀偤瀛ｉ姩楣藉瀷寮�(qi谩ng)闄介洟瀛愬瀷鑱氶浕瑙ｈ唱(zh矛)锛屾槸闈犲付寮�(qi谩ng)闄介浕鑽风殑澶у垎瀛愰張閫�(j矛n)琛屼腑鍜屻€佸惛闄�銆佹灦姗嬩締瀹屾垚绲嚌閬庣▼鐨勩€傝€屽ぇ鍒嗗瓙鍦ㄦ按涓憟瀹屽叏婧惰В鐙€鎱�(t脿i)涓旂敤閲忓緢灏�(鐩哥暥(d膩ng)浜庤仛鍚堟隘鍖栭媮(PAC) 鐢ㄩ噺鐨�10%锝�20%) 锛屽叾鏈韩涓嶆槸鐢�(ch菐n)鐢熸福婧愮殑鍥犵礌[9]銆傚畠鎵€鍏锋湁鐨勫挤(qi谩ng)闆讳腑鍜屾€ц兘鍙娇姘村寘娌逛钩娑茬牬澹�锛屾补鐝犺繀閫熶笂娴紝寤㈡按涓殑鎳告诞鐗╃诞鍑濇矇闄�锛屽洜鑰岃兘閬�(d谩)鍒扮悊鎯崇殑娌规按鍒嗛洟鏁堟灉銆�

鍚堟垚鑱氫簩鐢插熀浜岀儻涓欏熀姘寲閵�(PDMDAAC)鐨勬柟娉曟湁澶氱ó锛屽姘存憾娑茶仛鍚堛€佹湁姗�(j墨)鐩告憾娑茶仛鍚�銆佹矇娣€鑱氬悎銆佷钩娑茶仛鍚堝拰鎳告诞鑱氬悎绛�銆傝仛鍚堝弽鎳�(y墨ng)閬庣▼涓�锛屽偓鍖栧姂鐨勭敤閲忋€佷箼浜岃兒鍥涗箼閰哥殑婵冨害銆佽捣濮嬪柈楂旀績搴﹀拰闆滆唱(zh矛)鍚噺绛夊皪鑱氬悎鐗╃殑娈樹綑鍠珨閲忓拰绲嚌鑳藉姏鍧囨湁褰遍熆[10]銆傜緟韬峓11]浣跨敤鍙嶇浉涔虫恫鑱氬悎鏂规硶鍚堟垚PDMDAAC锛岀⒑瀹氬柈楂旀績搴︾偤45%锛屽柈楂旈厤姣旂偤7锛�3锛屽紩鐧�(f膩)婧害鐐�45 鈩�锛屽紩鐧�(f膩)鍔戠敤閲弇(寮曠櫦(f膩)鍔�) /m(鍠珨) 鐐�0锛�5%銆傚悎鎴愮敘(ch菐n)鍝佸皪娌圭敯姹℃按閫�(j矛n)琛岀诞鍑濇€ц兘瑭曞児锛屽叾鍠崹(d煤)浣跨敤鏅傛縼搴﹀幓闄ょ巼鐐�86锛�22%锛孋OD 鍘婚櫎鐜囩偤87锛�95%; 鐣�(d膩ng)鑸囪仛鍚堟隘鍖栭媮寰�(f霉)閰嶄娇鐢ㄦ檪婵佸害鐨勫幓闄ょ巼鐐�92锛�91%锛孋OD 鍘婚櫎鐜囩偤92锛�68%銆傚京(f霉)閰嶄娇鐢ㄦ瘮鍠崹(d煤)浣跨敤鏁堟灉鏇村ソ銆�

1.2.2 寰�(f霉)閰嶈仛浜岀敳鍩轰簩鐑笝鍩烘隘鍖栭姩椤�

鍒扮洰鍓嶇偤姝�锛岄倓娌掓湁鐧�(f膩)鐝�(xi脿n)鍦嬪闂�(gu膩n)浜庨媮(閻�) 楣�-PDMDAAC 鎴栭媮(閻�) 楣�-P(EPI-DMA) 绛夌劇姗�(j墨)锛嶆湁姗�(j墨)寰�(f霉)鍚堢诞鍑濆姂鐮旂┒鐨勫牨閬撱€傚湅鍏�(n猫i)杩戝勾渚嗘湁寰堝鐮旂┒鑰呴枊灞曚簡閶�(閻�) 楣�-PDMDAAC 鐒℃(j墨)-鏈夋(j墨)寰�(f霉)鍚堢诞鍑濆姂鐨勭爺绌跺拰闁嬬櫦(f膩)鎳�(y墨ng)鐢ㄥ伐浣淸12]銆傜帇鐜夊瑡[13]灏峆DMDAAC 鑸嘝AC 浠ヤ竴瀹氶噺寰�(f霉)閰嶏紝鎵€寰楃殑瀵�(sh铆)椹�(y脿n)鏁堟灉鑹ソ銆傚京(f霉)閰嶇殑绲嚌鏁堟灉瑕佹槑椤ソ浜庡柈涓€绲嚌鍔�锛屾渶楂橀€忓厜鐜囩偤98锛�0%锛屾按涓惈娌归噺鐐�6锛�8 mg /L銆傞緮绔归潚[14]鐢ㄨ仛鍚堢～閰搁惖鑸嘝DMDAAC寰�(f霉)閰�锛屽埗鍌欎簡绌�(w臎n)瀹氱殑鍧囩浉寰�(f霉)鍚堢诞鍑濆姂锛屽皪婵佸害锛孋OD锛宲H 鍒嗗垾鐐�105锛�2 mg /L锛�187锛�5 mg /L锛�7锛�59鐨勭敓娲绘薄姘撮€�(j矛n)琛岃檿鐞�锛屽湪鏈€浣崇敤閲忔檪锛屽京(f霉)鍚堢诞鍑濆姂涓璅e3 +鐨勭敤閲忔瘮鍠崹(d煤)浣跨敤PFS 閬�(d谩)鍒版渶浣虫晥鏋滄檪鐨勭敤閲忔笡灏戜簡27锛�07 mg /L锛孋OD 鍘婚櫎鐜囨彁楂樹簡12%銆�

1.3 鑱氱挵(hu谩n)姘ф隘涓欑兎鑸囪兒鐨勫弽鎳�(y墨ng)鐗╅

鐢ㄧ挵(hu谩n)姘ф隘涓欑兎(PECH) 鑸囦笉鍚岃兒鐨勮仛鍚堢墿浣滅偤姘磋檿鐞嗗姂鐨勭爺绌跺拰鎳�(y墨ng)鐢ㄧ洰鍓嶅湪鍦嬪収(n猫i)鍫遍亾寰堝皯锛岃垏鍦嬪鐩告瘮鏈夎純澶х殑宸窛[15]銆傞€欓闄介洟瀛愰珮鍒嗗瓙绲嚌鍔戣垏鍏朵粬闄介洟瀛愮诞鍑濆姂鐩告瘮锛屾渶澶х殑鐗归粸(di菐n)鏄畠鍊戣兘浣跨敤鍦ㄥ惈姘垎鏁ｇ浉鐨勬按鍒嗘暎楂斾腑鑰屼笉鑸囨隘鍖栫墿璧蜂綔鐢�锛屽緸鑰屽湪鍚隘鍒嗘暎鐩哥殑姘村垎鏁ｉ珨绯讳腑浣跨敤鏅備笉鏈冮檷浣庡叾绲嚌鏁堟灉銆傞棞(gu膩n)浜庤仛鐠�(hu谩n)姘ф隘涓欑兎鑸囪兒鐨勫弽鎳�(y墨ng)鐗╁彲浠ユ牴鎿�(j霉)鎵€浣跨敤鑳虹殑鎬ц唱(zh矛)涓嶅悓锛屼互寰楀埌涓嶅悓鍝佺ó銆佷笉鍚屾€ц兘鐨勯櫧闆㈠瓙绲嚌鍔�銆傚鑱�2-缇ヤ笝鍩�-1锛�1-N-浜岀敳鍩烘隘鍖栭姩锛屽畠鏄互浜岀敳鑳哄拰鐠�(hu谩n)姘ф隘涓欑兎鐐哄師鏂欙紝浠ユ按鐐烘憾鍔戦€�(j矛n)琛屾憾娑茶仛鍚堝緱鍒扮殑[16]銆傜暥(d膩ng)鐢ㄧ浉灏嶅垎瀛愯唱(zh矛)閲忕偤5脳104锝� 7锛�5脳104 鐨勬椤炵敘(ch菐n)鍝佽檿鐞嗙厜娌瑰粻鐨勫虎姘�锛屾晥鏋滆壇濂�銆傞珮鍜岃粛[17]閲囩敤浜岀敳鑳�銆佷箼浜岃兒鍙婂繁浜岃兒灏峆ECH 鎿�(ku貌)鑱�(li谩n)銆佷笁鐢茶兒瀛ｉ姩鍖栧弽鎳�(y墨ng)寰楀埌鑱氱挵(hu谩n)姘ф隘涓欑兎绲嚌鍔慞ECHA 绯诲垪?锛熺柧鐐濊枛ECHA 绯诲垪绲嚌鍔戝柈鐛�(d煤)鍜岃垏鐒℃(j墨)鐗╁京(f霉)閰嶈檿鐞嗕腑娴锋补鍗楁捣娼�11-4娌圭敯姹℃按鐨勬晥鏋溿€侾ECHA(鈪�) 鑸囨隘鍖栭媴寰�(f霉)鍚堜箣鍚庣殑闄ゆ补鐜囧彲閬�(d谩)鍒�87锛�1%銆�

1.4 鑱氫箼鐑挭鍞戝晧椤�

鑱氫箼鐑挭鍞戝晧[18]鐨勭爺绌跺湅鍏�(n猫i)鍫卞皫(d菐o)寰堝皯锛屽湅澶栧湪閫欏€嬫柟闈㈢殑鐮旂┒杓冨銆傚鍏锋湁涓€鍔戝鏁堜綔鐢ㄧ殑鑱�2-涔欑儻鍜攽鍟�锛屽畠鍖呮嫭鑱�2-涔欑儻鍜攽鍟�銆佽仛2-涔欑儻鍜攽鍟夌～閰�/楣介吀楣絒19]锛屽彲閲囩敤涔欎簩鑳鸿垏涓欑儻鑵堝悎鎴愭硶鍒跺緱銆傝仛锛� 2-涔欑儻鍜攽鍟夊彲鐢ㄤ簬姘寸殑鍑堝寲鍜屾薄娉ヨ劔姘磋檿鐞�锛岀壒鍒ラ仼瀹滈櫎鍘绘按涓殑闄伴洟瀛愭按婧剁墿锛屽彲鑸囩劇姗�(j墨)娣峰嚌鍔戝京(f霉)閰嶄娇鐢�銆傜暥(d膩ng)鐢ㄤ簬姹℃偿鑴按涓紝涓嶅儏鍏锋湁鎶曞姞閲忓皬(鐩告噳(y墨ng)姹℃偿鐢�(ch菐n)鐢熼噺灏�) 锛岃€屼笖閭勬湁鑴按蹇劔姘撮噺澶х瓑鍎�(y艒u)鐣版€ц兘锛屾槸鐒℃(j墨)绲嚌鍔戠劇娉曟瘮鎿殑銆傞櫎鐢ㄤ綔绲嚌鍔戝锛屽垎瀛愰噺浣庣殑鐢�(ch菐n)鍝佷篃鍙互鐢ㄤ綔绶╄潟鍔戝拰鐮翠钩鍔�銆�

2 闄介洟瀛愬瀷澶╃劧鏈夋(j墨)楂樺垎瀛愮诞鍑濆姂

闄介洟瀛愬瀷澶╃劧鏈夋(j墨)楂樺垎瀛愮诞鍑濆姂浠ュ叾鍎�(y艒u)鑹殑绲嚌鎬�銆佸畨鍏ㄦ€с€佸師鏂欎締婧愬唬娉涗笖鍍规牸浣庡粔绛夌壒榛�(di菐n)椤ず鍑鸿壇濂界殑鎳�(y墨ng)鐢ㄥ墠鏅痆20]銆傛椤炵诞鍑濆姂鏇村鐨勬槸灏嶅ぉ鐒舵湁姗�(j墨)楂樺垎瀛愭敼鎬ф彁楂樼敘(ch菐n)鍝佺殑绲嚌鎬ц兘銆傜偤浜嗛檷浣庡師娌归枊閲囨垚鏈�锛屽悓鏅傛彁楂樻按铏曠悊鍔戠殑鍑堟按鏁堢巼锛屾笡灏戣檿鐞嗚不(f猫i)鐢ㄤ互鍙婁簩娆℃薄鏌�锛屾椤炵诞鍑濆姂鍏锋湁涓€瀹氱殑鐧�(f膩)灞曠┖闁�銆�

2.1 娈艰仛绯栭

鐢叉绱犵稉(j墨ng)鑴箼?锛涱垇骞氱牀锜帿闄嶆紶a(ch菐n)鐗╂鑱氱硸鍙兘鍦ㄩ吀鎬ф按婧舵恫涓憾瑙�锛屼笖绲嚌鎬ц兘娆犱匠锛屼娇鍏舵噳(y墨ng)鐢ㄥ彈鍒伴檺鍒�銆傚洜姝や汉鍊戝皪鍏堕€�(j矛n)琛屼笉鏂风殑鏀规€т締鎻愰珮鍏舵€ц兘銆傛鑱氱硸鍒嗗瓙绲�(ji茅)妲�(g貌u)涓湁寰堝鐨勨€擭H2鍜屸€擮H锛屽垎瀛愪笂娲昏簫鐨勨€擭H2鑸囨按閲岀殑H + 璩�(zh矛)瀛愬寲褰㈡垚闄介洟瀛愯仛鍚堥浕瑙ｈ唱(zh矛)锛屽皪浜庡惈娌规薄姘村幓闄OD锛孲S 鍜岄噾灞洟瀛愶紝鏁堢巼鏇撮珮銆傚缈犵帀绛塠21]鐢�2锛�3锛嶇挵(hu谩n)姘т笝鍩轰笁鐢插熀姘寲閵ㄥ皪娈艰仛绯栭€�(j矛n)琛屽寲瀛�(xu茅)鏀规€�锛屽緱鍒版鑱氱硸瀛ｉ姩楣界诞鍑濆姂銆傝檿鐞嗗嫕鍒╁宄舵补鐢板涓€銆佸浜旂珯姹℃按锛孭AC 鐢ㄩ噺60 mg /L锛岀暥(d膩ng)娈艰仛绯栧閵ㄩ菇鐢ㄩ噺鐢�2 mg /L 澧炲姞鑷�6 mg /L 鏅�锛屽涓€绔�銆佸浜旂珯姹℃按鍑堟按鏁堟灉鍒嗗垾鎻愰珮95锛�1% 鍜�91锛�0%銆�

闄や簡灏嶆鑱氱硸鏀规€т箣澶�锛岄倓鏈夊氨鏄噰鐢ㄦ鑱氱硸鍜岀劇姗�(j墨)鎴栬€呮湁姗�(j墨)绲嚌鍔戝京(f霉)閰嶃€佸京(f霉)鍚�锛屼篃鍏锋湁杓冨挤(qi谩ng)鐨勬噳(y墨ng)鐢ㄦ€с€俍eng 绛塠22]浠ユ鑱氱硸銆丳AC銆佺閰搁菇鍒跺緱寰�(f霉)鍚堢诞鍑濆姂锛屽湪鍚屾ǎ鐨勬浠朵笅铏曠悊寤㈡按锛岃垏PAC 鐩告瘮锛孋OD锛孲S锛孉l3 + 鐨勫幓闄ょ巼鑳藉鍒嗗垾鎻愰珮1锛�8% 锝� 23锛�7%锛�50% 鍜�61锛�2% 锝� 85锛�5%锛屾垚鏈笅闄�7% 锝� 34%銆備竵浠曞挤(qi谩ng)[22]閲囩敤娈艰仛绯栧拰PAM(鑱氫笝鐑叞鑳�) 鑱�(li谩n)鍚堜娇鐢ㄧ殑鏂规硶铏曠悊鍚补寤㈡按: pH 鐐�7锛孭AM 閲忕偤1 mg /L锛屾鑱氱硸閲忕偤8 mg /L 鏅傦紝婵佸害鍘婚櫎鐜囧彲閬�(d谩)91锛�7%銆�

2.2 鏀规€ф穩绮夐

鐢变簬姘磋檿鐞嗕腑澶ч儴鍒嗗井绱�(x矛)椤嗙矑鍜岃啝楂旈兘甯舵湁璨�(f霉)闆昏嵎锛屽皪娣€绮夐€�(j矛n)琛岄櫧闆㈠瓙鏀规€у悗锛屽叾娲绘€у熀鍦�(tu谩n)鏁�(sh霉)鐩ぇ澶у鍔�锛岃仛鍚堢墿鍛堟灊鍖栫祼(ji茅)妲�(g貌u)锛屽垎鏁ｇ殑绲嚌鍩哄湗(tu谩n)灏嶆嚫娴珨绯讳腑椤嗙矑鐗╂湁杓冨挤(qi谩ng)鐨勬崟鎹夎垏淇冩矇浣滅敤[23]銆傚妷璨存瘏绛塠24]鐢ㄦ敼鎬х帀绫虫穩绮夌诞鍑濆姂灏嶅惈娌瑰虎姘磋檿鐞�锛屽姞钘ラ噺鐐�12 mg /L锛屽皪COD 鐨勫幓闄ょ巼鍙仈(d谩)77锛�94%锛屽皪鐭虫补椤炵殑鍘婚櫎鐜囧彲閬�(d谩)61锛�2%锛岃檿鐞嗗悗姘磋唱(zh矛)閫忓厜鐜囧彲閬�(d谩)62锛�7%锛屽皪SS 鍘婚櫎鐜囧彲閬�(d谩)79锛�96%?锛熸ⅱ閽ラ棷榘ь瀱顑噣楝唽濂跺箽鐮搨灞戦搥骞滃悍?锛岃檿鐞嗘晥鏋滃ソ鐨勫劒(y艒u)榛�(di菐n)銆傞瀣孾25] 浠�(NH4)2S2O8 /NaHSO3鐐烘哀鍖栭倓鍘熼珨绯�锛屽湪娣€绮夋帴鏋滱M 鐨勫熀绀�(ch菙)涓�锛屽紩閫�(j矛n)闄介洟瀛愬柈楂擠ADMAC锛屽悎鎴愰櫧闆㈠瓙娣€绮夋敼鎬х诞鍑濆姂SC1绛�銆傜～閰搁媮鑸囨穩绮夋敼鎬х诞鍑濆姂寰�(f霉)閰嶈檿鐞嗗ぇ鎱朵笁鍏冨京(f霉)鍚堥﹨(q奴)娌圭敯姹℃按锛岄櫧闆㈠瓙娣€绮夋敼鎬х诞鍑濆姂鐨勭诞鍑濇晥鏋滃ソ浜庨潪闆㈠瓙娣€绮夋敼鎬х诞鍑濆姂銆傚湪50 mg /L SC1鏅�锛屾补銆佽仛鍚堢墿銆佹嚫娴墿鍚噺鍧囬仈(d谩)鍒扮悊鎯虫晥鏋溿€�

2.3 鏈ㄨ唱(zh矛)绱犻

鏈ㄨ唱(zh矛)绱犱綔鐐烘鐗╀腑铇�(y霉n)钘忛噺鍍呮浜庣簴缍礌鐨勯珮鑱氱墿锛屾槸涓€绋粔鍍规槗寰�銆佸劜閲忚睈瀵�銆佺挵(hu谩n)澧冨弸濂界殑鍙啀鐢熷ぉ鐒惰硣婧愩€傚悓鏅�锛屽畠涔熸槸閫犵礄榛戞恫鐨勪富瑕佹垚鍒�銆傜爺绌惰€呭埄鐢ㄦ湪璩�(zh矛)绱犲垎瀛愮祼(ji茅)妲�(g貌u)闈炲父寰�(f霉)闆滅殑鐗归粸(di菐n)锛屽皣鍏舵敼鎬т娇鍏跺舰鎴愭洿澶氱殑娲绘€у熀鍦�(tu谩n)锛岀劧鍚庡啀鑸囦竴浜涘柈楂旇仛鍚堝埗寰楃壒娈婂姛鑳界殑姘磋檿鐞嗗姂銆傛鏋梉26]浠ュ牽鏈ㄧ礌鐐哄師鏂�锛岄€氶亷鍖栧(xu茅)鏀规€�锛屽埗鍌欏嚭鍚簩纭唬姘ㄥ熀鐢查吀楣藉熀鍦�(tu谩n)鐨勬敼鎬ф湪璩�(zh矛)绱犻櫎娌圭诞鍑濆姂銆傜暥(d膩ng)鍚补寤㈡按鐨刾H 鐐�6锛�7锛岀诞鍑濆姂鐨勮唱(zh矛)閲忔績搴︾偤35 mg /L 鏅�锛屽虎姘翠腑鐨勬补銆丆ODCr銆佸浐楂旀嚫娴墿鍜岃壊搴︾殑鍘婚櫎鐜囧垎鍒ラ仈(d谩)鍒�88锛�2%锛�71锛�5%锛�90锛�5%鍜�93锛�7%銆傦紝缍�(j墨ng)灏嶆瘮鍏剁诞鍑濇€ц兘鏄庨’鍎�(y艒u)浜嶱AM锛孭AC 鍜岃仛鍚堢～閰搁惖绛夐珮鍒嗗瓙绲嚌鍔�銆�

3 绲�(ji茅)鏉熻獮

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[1] 鍞愮搳锛屽嫉鏂扮敵锛屾潕姝ｅ北锛庢补鐢板惈娌瑰虎姘磋檿鐞嗙诞鍑濆姂鐨勭爺绌惰垏鎳�(y墨ng)鐢╗J]锛庡寲瀛�(xu茅)鐮旂┒鍙婃噳(y墨ng)鐢�锛�2002锛�14(6) : 641-644锛�

[2] 寰愭泬杌嶏紟鍖栧(xu茅)绲嚌鍔戜綔鐢ㄥ師鐞哰M]锛庡寳浜�: 绉戝(xu茅)鍑虹増绀撅紝2005: 88锛�

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